Crystal structure of 1,4-bis(triiodogallium(III))-1,4-bis(2,4,6-tri-tertbutylphenyl)-1,4-diphosphabuta-1,3-diene
The crystal-structure properties of [(I3Ga)2{P(C6H2But 3-2,4,6)CH}2]·(C7H8) are: monoclinic, space group C2/c with a = 17.506(4)Å, b = 14.799(3)Å, c = 22.861(5)Å, b = 104.85(3)°, V = 5725(2)Å3, Z = 4, R1 = 0.0735, wR2 = 0.1781 for 3869 reflections (I > 2σ(I)). The title compound represents th...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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| Summary: | The crystal-structure properties of [(I3Ga)2{P(C6H2But 3-2,4,6)CH}2]·(C7H8) are: monoclinic, space group C2/c with a = 17.506(4)Å, b = 14.799(3)Å, c = 22.861(5)Å, b = 104.85(3)°, V = 5725(2)Å3, Z = 4, R1 = 0.0735, wR2 = 0.1781 for 3869 reflections (I > 2σ(I)). The title compound represents the first structurally characterized complex of a 1,4-diphosphabutadiene with a main-group metal fragment. 2008 © The Japan Society for Analytical Chemistry. |
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