Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
Main Authors: | , |
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Format: | Journal article |
Language: | English |
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Royal Society of Chemistry
2015
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_version_ | 1797076298611294208 |
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author | Sidera, M Fletcher, S |
author_facet | Sidera, M Fletcher, S |
author_sort | Sidera, M |
collection | OXFORD |
description | Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products. |
first_indexed | 2024-03-07T00:02:05Z |
format | Journal article |
id | oxford-uuid:764be43c-532f-4bde-a740-b9e6519ff4c3 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T00:02:05Z |
publishDate | 2015 |
publisher | Royal Society of Chemistry |
record_format | dspace |
spelling | oxford-uuid:764be43c-532f-4bde-a740-b9e6519ff4c32022-03-26T20:14:52ZCu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromidesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:764be43c-532f-4bde-a740-b9e6519ff4c3EnglishORA DepositRoyal Society of Chemistry2015Sidera, MFletcher, SAlkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products. |
spellingShingle | Sidera, M Fletcher, S Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title | Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title_full | Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title_fullStr | Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title_full_unstemmed | Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title_short | Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides |
title_sort | cu catalyzed asymmetric addition of sp2 hybridized zirconium nucleophiles to racemic allyl bromides |
work_keys_str_mv | AT sideram cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides AT fletchers cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides |