Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.

Bibliographic Details
Main Authors: Sidera, M, Fletcher, S
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2015
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author Sidera, M
Fletcher, S
author_facet Sidera, M
Fletcher, S
author_sort Sidera, M
collection OXFORD
description Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
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institution University of Oxford
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spelling oxford-uuid:764be43c-532f-4bde-a740-b9e6519ff4c32022-03-26T20:14:52ZCu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromidesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:764be43c-532f-4bde-a740-b9e6519ff4c3EnglishORA DepositRoyal Society of Chemistry2015Sidera, MFletcher, SAlkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
spellingShingle Sidera, M
Fletcher, S
Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title_full Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title_fullStr Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title_full_unstemmed Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title_short Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
title_sort cu catalyzed asymmetric addition of sp2 hybridized zirconium nucleophiles to racemic allyl bromides
work_keys_str_mv AT sideram cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides
AT fletchers cucatalyzedasymmetricadditionofsp2hybridizedzirconiumnucleophilestoracemicallylbromides