Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí: Sidera, M, Fletcher, S
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: Royal Society of Chemistry 2015