Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides

Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.

書目詳細資料
Main Authors:	Sidera, M, Fletcher, S
格式:	Journal article
語言:	English
出版:	Royal Society of Chemistry 2015

相似書籍

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
由: Sidera, M, et al.
出版: (2015)

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
由: Schafer, P, et al.
出版: (2017)

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials
由: Rideau, E, et al.
出版: (2017)

Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation
由: You, H, et al.
出版: (2015)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
由: Sidera, M, et al.
出版: (2015)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
由: Schäfer, P, et al.
出版: (2017)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
由: Philipp Schäfer, et al.
出版: (2017-06-01)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
由: Philipp Schäfer, et al.
出版: (2018-05-01)

Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
由: Fletcher, S
出版: (2019)

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs
由: Lou, Sha, et al.
出版: (2011)

Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones
由: Tsuyoshi Mita, et al.
出版: (2018-08-01)

Non-stabilized nucleophiles in cu-catalyzed asymmetric synthesis
由: You, H
出版: (2016)

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
由: González, J, et al.
出版: (2019)

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
由: Lee, Hong Geun, et al.
出版: (2015)

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones
由: Lu, G., et al.
出版: (2018)

Copper catalyzed asymmetric synthesis of chiral allylic esters.
由: Geurts, K, et al.
出版: (2006)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
由: Emeline Rideau, et al.
出版: (2015-12-01)

Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.
由: Sidera, M, et al.
出版: (2013)

The Copper-Catalyzed Asymmetric Allylic Substitution
由: Alexandre Alexakis, et al.
出版: (2006-03-01)

Asymmetric synthesis of nortropanes via Rh-catalyzed allylic arylation
由: Zhang, Y, et al.
出版: (2022)

The Amino Thiourea-Catalyzed Asymmetric Nucleophilic Reactions
由: Yoshiji Takemoto, et al.
出版: (2007-05-01)

Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.
由: Roth, P, et al.
出版: (2014)

Desymmetrization of meso-bisphosphates via rhodium catalyzed asymmetric allylic arylation
由: Jacques, R, et al.
出版: (2019)

Additions to racemates: a strategy for developing asymmetric cross-coupling reactions
由: Goetzke, F, et al.
出版: (2021)

Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
由: Geurts, K, et al.
出版: (2008)

Nucleophilic additions of chiral non-racemic enolates to N-benzyl-C-(alkoxymethyl) nitrones
由: Pedro Merino, et al.
出版: (2003-12-01)

Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile
由: Gribble, Michael William, et al.
出版: (2020)

Kinetic and dynamic kinetic resolution of racemic tertiary bromides by pentanidium‐catalyzed phase‐transfer azidation
由: Ren, Jingyun, et al.
出版: (2023)

Enantioselective arylation and vinylation of allylic bromides catalyzed by guanidinium and copper(I) salt
由: Jiang, Huan
出版: (2018)

Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile
由: D. Matthew Peacock, et al.
出版: (2016-09-01)

Catalytic Enantioselective Cross-Couplings of Secondary Alkyl Electrophiles with Secondary Alkylmetal Nucleophiles: Negishi Reactions of Racemic Benzylic Bromides with Achiral Alkylzinc Reagents
由: Cordier, Christopher J., et al.
出版: (2013)

Asymmetric allylic alkynylation catalyzed by guanidine copper(I) complex
由: Cui, Xiyang
出版: (2018)

Copper(I)/guanidine catalyzed asymmetric allylic borylation reaction
由: Ge, Yicen
出版: (2018)

Chalcogen-containing oxazolines in the palladium-catalyzed asymmetric allylic alkylation
由: Braga Antonio L., et al.
出版: (2006-01-01)

Copper(I)-catalyzed asymmetric 1,6-conjugate allylation
由: Chang-Yun Shi, et al.
出版: (2020-10-01)

Asymmetric nucleophilic addition to vinylphosphonamidates (Part IV)
由: Kamyar Afarinkia, et al.
出版: (2002-10-01)

Synthesis of the taxol core via catalytic asymmetric 1,4-addition of an Alkylzirconium Nucleophile
由: Wang, JYJ, et al.
出版: (2020)

Iridium-Catalyzed Asymmetric Ring-Opening of Oxabenzonorbornadienes with N-Substituted Piperazine Nucleophiles
由: Wen Yang, et al.
出版: (2015-11-01)

Rhodium-Catalyzed Tandem Asymmetric Allylic Decarboxylative Addition and Cyclization of Vinylethylene Carbonates with <i>N</i>-Nosylimines
由: Xiao-Lin Wang, et al.
出版: (2024-02-01)

Asymmetric remote C-H functionalization: use of internal olefins in tandem hydrometallation-isomerization-asymmetric conjugate addition sequences
由: Mola, L, et al.
出版: (2015)