Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes.
(Chemical Equatation Reprentation An (Au)some coupling! Gold-catalyzed cascade C-O cyclizations of benzyl-substituted allenoate esters followed by intramolecular oxidative C-C cross-coupling involving aryl C-H functionalization were performed with Selectfluor as the oxidant (see scheme). This operat...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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| _version_ | 1826279802161594368 |
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| author | Hopkinson, M Tessier, A Salisbury, A Giuffredi, G Combettes, L Gee, A Gouverneur, V |
| author_facet | Hopkinson, M Tessier, A Salisbury, A Giuffredi, G Combettes, L Gee, A Gouverneur, V |
| author_sort | Hopkinson, M |
| collection | OXFORD |
| description | (Chemical Equatation Reprentation An (Au)some coupling! Gold-catalyzed cascade C-O cyclizations of benzyl-substituted allenoate esters followed by intramolecular oxidative C-C cross-coupling involving aryl C-H functionalization were performed with Selectfluor as the oxidant (see scheme). This operationally simple and mild procedure benefits from complete axis-to-center chirality transfer and allows for the preparation of surprisingly uncommon tricyclic motifs. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T00:04:13Z |
| format | Journal article |
| id | oxford-uuid:76fc43c3-7a91-4dae-91ba-e7dd9b040898 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:04:13Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:76fc43c3-7a91-4dae-91ba-e7dd9b0408982022-03-26T20:20:09ZGold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:76fc43c3-7a91-4dae-91ba-e7dd9b040898EnglishSymplectic Elements at Oxford2010Hopkinson, MTessier, ASalisbury, AGiuffredi, GCombettes, LGee, AGouverneur, V(Chemical Equatation Reprentation An (Au)some coupling! Gold-catalyzed cascade C-O cyclizations of benzyl-substituted allenoate esters followed by intramolecular oxidative C-C cross-coupling involving aryl C-H functionalization were performed with Selectfluor as the oxidant (see scheme). This operationally simple and mild procedure benefits from complete axis-to-center chirality transfer and allows for the preparation of surprisingly uncommon tricyclic motifs. © 2010 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Hopkinson, M Tessier, A Salisbury, A Giuffredi, G Combettes, L Gee, A Gouverneur, V Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title | Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title_full | Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title_fullStr | Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title_full_unstemmed | Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title_short | Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes. |
| title_sort | gold catalyzed intramolecular oxidative cross coupling of nonactivated arenes |
| work_keys_str_mv | AT hopkinsonm goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT tessiera goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT salisburya goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT giuffredig goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT combettesl goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT geea goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes AT gouverneurv goldcatalyzedintramolecularoxidativecrosscouplingofnonactivatedarenes |