SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS
Spectrofluorimetric hydrodynamic voltammetry (SFV) is used to study the electroreduction of crystal violet in acetonitrile solution. The SFV technique is shown to have high sensitivity and to complement conventional electrochemical experiments through its identification of leucocrystal violet as an...
| Үндсэн зохиолчид: | , |
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| Формат: | Journal article |
| Хэл сонгох: | English |
| Хэвлэсэн: |
1994
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| _version_ | 1826279887493660672 |
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| author | Compton, R Wellington, R |
| author_facet | Compton, R Wellington, R |
| author_sort | Compton, R |
| collection | OXFORD |
| description | Spectrofluorimetric hydrodynamic voltammetry (SFV) is used to study the electroreduction of crystal violet in acetonitrile solution. The SFV technique is shown to have high sensitivity and to complement conventional electrochemical experiments through its identification of leucocrystal violet as an electrolysis product generated in low concentration in addition to the radical species formed as a one-electron adduct of the parent compound and previously thought to be produced exclusively. Mechanistic SFV studies show that the leucocrystal violet is formed via an EC process for which kinetic parameters are reported. © 1994 American Chemical Society. |
| first_indexed | 2024-03-07T00:05:30Z |
| format | Journal article |
| id | oxford-uuid:77668ca6-ff76-421c-97b4-915787f8d9f9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:05:30Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:77668ca6-ff76-421c-97b4-915787f8d9f92022-03-26T20:23:46ZSPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:77668ca6-ff76-421c-97b4-915787f8d9f9EnglishSymplectic Elements at Oxford1994Compton, RWellington, RSpectrofluorimetric hydrodynamic voltammetry (SFV) is used to study the electroreduction of crystal violet in acetonitrile solution. The SFV technique is shown to have high sensitivity and to complement conventional electrochemical experiments through its identification of leucocrystal violet as an electrolysis product generated in low concentration in addition to the radical species formed as a one-electron adduct of the parent compound and previously thought to be produced exclusively. Mechanistic SFV studies show that the leucocrystal violet is formed via an EC process for which kinetic parameters are reported. © 1994 American Chemical Society. |
| spellingShingle | Compton, R Wellington, R SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title | SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title_full | SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title_fullStr | SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title_full_unstemmed | SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title_short | SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS |
| title_sort | spectrofluorometric hydrodynamic voltammetry the investigation of electrode reaction mechanisms |
| work_keys_str_mv | AT comptonr spectrofluorometrichydrodynamicvoltammetrytheinvestigationofelectrodereactionmechanisms AT wellingtonr spectrofluorometrichydrodynamicvoltammetrytheinvestigationofelectrodereactionmechanisms |