Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes
The voltammetric behavior of glassy carbon electrodes modified with either submonolayer quantities of alumina or graphene is examined with respect to the two-electron, two-proton reaction of catechol (1,2-dihydroxybenzene) in aqueous solution. While the voltammetric behavior superficially hints at a...
| Main Authors: | , , , , , |
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| Format: | Journal article |
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2015
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| _version_ | 1826279936250347520 |
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| author | Poon, J Lin, Q Batchelor-McAuley, C Salter, C Johnston, C Compton, R |
| author_facet | Poon, J Lin, Q Batchelor-McAuley, C Salter, C Johnston, C Compton, R |
| author_sort | Poon, J |
| collection | OXFORD |
| description | The voltammetric behavior of glassy carbon electrodes modified with either submonolayer quantities of alumina or graphene is examined with respect to the two-electron, two-proton reaction of catechol (1,2-dihydroxybenzene) in aqueous solution. While the voltammetric behavior superficially hints at a change of electron transfer rate, an alternative explanation in terms of the changed thermodynamics of the intermediate species is advanced and rationalized. |
| first_indexed | 2024-03-07T00:06:15Z |
| format | Journal article |
| id | oxford-uuid:77a35296-1385-4a9a-a8e3-3336656bccb8 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T00:06:15Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | oxford-uuid:77a35296-1385-4a9a-a8e3-3336656bccb82022-03-26T20:25:26ZAltered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode ProcessesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:77a35296-1385-4a9a-a8e3-3336656bccb8Symplectic Elements at Oxford2015Poon, JLin, QBatchelor-McAuley, CSalter, CJohnston, CCompton, RThe voltammetric behavior of glassy carbon electrodes modified with either submonolayer quantities of alumina or graphene is examined with respect to the two-electron, two-proton reaction of catechol (1,2-dihydroxybenzene) in aqueous solution. While the voltammetric behavior superficially hints at a change of electron transfer rate, an alternative explanation in terms of the changed thermodynamics of the intermediate species is advanced and rationalized. |
| spellingShingle | Poon, J Lin, Q Batchelor-McAuley, C Salter, C Johnston, C Compton, R Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title | Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title_full | Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title_fullStr | Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title_full_unstemmed | Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title_short | Altered Electrochemistry at Graphene- or Alumina-Modified Electrodes: Catalysis vs Electrocatalysis in Multistep Electrode Processes |
| title_sort | altered electrochemistry at graphene or alumina modified electrodes catalysis vs electrocatalysis in multistep electrode processes |
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