Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes
Adducts with MoO42- tetrahedra coordinated to Cr(III) or Co(III) complexes have been synthesised and studied by IR and high resolution 95Mo NMR spectroscopy. The 95Mo chemical shifts of the adducts with cobalt(III) lie in the range -33.2 to +49.4 ppm. This may be compared with an overall known chemi...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1997
|
| _version_ | 1797076623304949760 |
|---|---|
| author | Holder, A Dasgupta, T McFarlane, W Rees, N Enemark, J Pacheco, A Christensen, K |
| author_facet | Holder, A Dasgupta, T McFarlane, W Rees, N Enemark, J Pacheco, A Christensen, K |
| author_sort | Holder, A |
| collection | OXFORD |
| description | Adducts with MoO42- tetrahedra coordinated to Cr(III) or Co(III) complexes have been synthesised and studied by IR and high resolution 95Mo NMR spectroscopy. The 95Mo chemical shifts of the adducts with cobalt(III) lie in the range -33.2 to +49.4 ppm. This may be compared with an overall known chemical shift range in excess of 7000 ppm and implies a similarity in the molybdenum environment in all cases. For adducts with chelated cobalt(IH) complexes several rather broad 95Mo signals are obtained with linewidths up to 260 Hz. |
| first_indexed | 2024-03-07T00:06:21Z |
| format | Journal article |
| id | oxford-uuid:77ab4986-7a21-4284-ba22-3a08f0370e36 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:06:21Z |
| publishDate | 1997 |
| record_format | dspace |
| spelling | oxford-uuid:77ab4986-7a21-4284-ba22-3a08f0370e362022-03-26T20:25:40ZSyntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:77ab4986-7a21-4284-ba22-3a08f0370e36EnglishSymplectic Elements at Oxford1997Holder, ADasgupta, TMcFarlane, WRees, NEnemark, JPacheco, AChristensen, KAdducts with MoO42- tetrahedra coordinated to Cr(III) or Co(III) complexes have been synthesised and studied by IR and high resolution 95Mo NMR spectroscopy. The 95Mo chemical shifts of the adducts with cobalt(III) lie in the range -33.2 to +49.4 ppm. This may be compared with an overall known chemical shift range in excess of 7000 ppm and implies a similarity in the molybdenum environment in all cases. For adducts with chelated cobalt(IH) complexes several rather broad 95Mo signals are obtained with linewidths up to 260 Hz. |
| spellingShingle | Holder, A Dasgupta, T McFarlane, W Rees, N Enemark, J Pacheco, A Christensen, K Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title | Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title_full | Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title_fullStr | Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title_full_unstemmed | Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title_short | Syntheses, characterisation, infrared and Mo-95 NMR spectroscopy of some coordinated oxo-molybdenum(VI) complexes |
| title_sort | syntheses characterisation infrared and mo 95 nmr spectroscopy of some coordinated oxo molybdenum vi complexes |
| work_keys_str_mv | AT holdera synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT dasguptat synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT mcfarlanew synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT reesn synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT enemarkj synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT pachecoa synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes AT christensenk synthesescharacterisationinfraredandmo95nmrspectroscopyofsomecoordinatedoxomolybdenumvicomplexes |