Enantioselective organocatalytic aldol reaction of ynones and its synthetic applications.
[Structure: see text] For the first time, unmodified ynones were used in organocatalytic asymmetric aldol reactions delivering monoprotected anti-alpha,beta-dihydroxyynones in high yields, dr's up to 19:1, and ee's up to 95%. These products can be either reduced to afford enantioenriched u...
Κύριοι συγγραφείς: | Silva, F, Sawicki, M, Gouverneur, V |
---|---|
Μορφή: | Journal article |
Γλώσσα: | English |
Έκδοση: |
2006
|
Παρόμοια τεκμήρια
Παρόμοια τεκμήρια
-
ORGN 25-Direct organocatalytic asymmetric addition of enones and ynones to aldehydes
ανά: Silva, F, κ.ά.
Έκδοση: (2006) -
Exploring Free Energy Profiles of Enantioselective Organocatalytic Aldol Reactions under Full Solvent Influence
ανά: Moritz Weiß, κ.ά.
Έκδοση: (2020-12-01) -
Improving enantioselectivity via rationally tuning electronic effect of catalysts in the organocatalytic asymmetric aldol reaction
ανά: Juanjuan Du, κ.ά.
Έκδοση: (2009-01-01) -
Organocatalytic Packed-Bed Reactors for the Enantioselective Flow Synthesis of Quaternary Isotetronic Acids by Direct Aldol Reactions of Pyruvates
ανά: Lorenzo Poletti, κ.ά.
Έκδοση: (2025-01-01) -
Organocatalytic Asymmetric Aldol Reaction of Arylglyoxals and Hydroxyacetone: Enantioselective Synthesis of 2,3-Dihydroxy-1,4-diones
ανά: Yu-Hao Zhou, κ.ά.
Έκδοση: (2020-02-01)