Enantioselective organocatalytic aldol reaction of ynones and its synthetic applications.

[Structure: see text] For the first time, unmodified ynones were used in organocatalytic asymmetric aldol reactions delivering monoprotected anti-alpha,beta-dihydroxyynones in high yields, dr's up to 19:1, and ee's up to 95%. These products can be either reduced to afford enantioenriched u...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Silva, F, Sawicki, M, Gouverneur, V
التنسيق: Journal article
اللغة:English
منشور في: 2006