Analytic continuation of Wolynes theory into the Marcus inverted regime
The Wolynes theory of electronically nonadiabatic reaction rates [P. G. Wolynes, J. Chem. Phys. 87, 6559 (1987)] is based on a saddle point approximation to the time integral of a reactive flux autocorrelation function in the nonadiabatic (golden rule) limit. The dominant saddle point is on the imag...
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| Médium: | Journal article |
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AIP Publishing
2017
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