Biomimetic rearrangements of simplified labdane diterpenoids
Simplified ethyl-substituted labdane diterpenoids 14 and 19 have been synthesised from (+)-sclareolide (18). Biomimetic rearrangements of these compounds, involving stereospecific 1,2-alkyl and hydride shifts, have been carried out by treatment with a variety of Lewis and protic acids. Halimane comp...
Main Authors: | George, J, McArdle, M, Baldwin, J, Adlington, R |
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Format: | Conference item |
Published: |
2010
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