Regio- and enantioselective synthesis of allylic fluorides by electrophilic fluorodesilylation of allyl silanes.

Regio- and enantioselective synthesis of allylic fluorides by electrophilic fluorodesilylation of allyl silanes.

Enantiopure N-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silanes in a conceptually new approach to the regio- and enantioselective formation of allylic fluorides (see scheme). Excellent conversions were observed in these reactions, which afforded the desired ally...

書目詳細資料
Main Authors:	Greedy, B, Paris, J, Vidal, T, Gouverneur, V
格式:	Journal article
語言:	English
出版:	2003

相似書籍

Electrophilic fluorodesilylation of allylsilanes: A mild synthetic route to allylic fluorides.
由: Greedy, B, et al.
出版: (2002)

Sequential cross-metathesis/electrophilic fluorodesilylation: a novel entry to functionalized allylic fluorides.
由: Thibaudeau, S, et al.
出版: (2003)

Electrophilic fluorocyclization of allyl silanes.
由: Wilkinson, S, et al.
出版: (2009)

Synthetic applications of electrophilic fluorodesilylation
由: Gouverneur, V, et al.
出版: (2002)

Synthetic applications of electrophilic fluorodesilylation.
由: Gouverneur, V, et al.
出版: (2002)

Regio- and stereoretentive synthesis of branched, linear (E)- and (Z)-allyl fluorides from allyl carbonates under Ir-catalysis
由: Benedetto, E, et al.
出版: (2013)

Electrophilic fluorocyclization vs. electrophilic fluorodesilylation
由: Pacheco, M, et al.
出版: (2005)

Preparation of Allylic Fluorides
由: Gouverneur, V, et al.
出版: (2012)

Stereoselective synthesis of internal allylic fluorides.
由: Thibaudeau, S, et al.
出版: (2004)

The chemistry of propargylic and allylic fluorides.
由: Pacheco, M, et al.
出版: (2008)

Palladium-catalyzed substitution of allylic fluorides.
由: Hazari, A, et al.
出版: (2009)

A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes
由: Tsai, Erica Y., et al.
出版: (2020)

Platinum-catalyzed substitution of allylic fluorides
由: Benedetto, E, et al.
出版: (2012)

Platinum-Catalyzed Substitution of Allylic Fluorides
由: Benedetto, E, et al.
出版: (2012)

Fluorous synthesis of allylic fluorides: C-F bond formation as the detagging process.
由: Boldon, S, et al.
出版: (2008)

Synthesis of 3-fluoropyrrolidines and 4-fluoropyrrolidin-2-ones from allylic fluorides.
由: Combettes, L, et al.
出版: (2012)

Synthesis and synthetic applications of allylic monofluorides
由: Pacheco, M, et al.
出版: (2006)

Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers
由: Greedy, B, et al.
出版: (2001)

Synthesis and reactivity of allylic fluorides under transition metal catalysis
由: Benedetto, E
出版: (2013)

Electrophilic fluorodesilylation of allenylmethylsilanes: a novel entry to 2-fluoro-1,3-dienes.
由: Pacheco, M, et al.
出版: (2005)

Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
由: Fletcher, S
出版: (2019)

Palladium catalyzed allylic fluorination
由: Hollingworth, C, et al.
出版: (2012)

Amine-linked diglycosides: Synthesis facilitated by the enhanced reactivity of allylic electrophiles, and glycosidase inhibition assays.
由: Cumpstey, I, et al.
出版: (2011)

Palladacycle-catalyzed tandem allylic amination/allylation protocol for one-pot synthesis of 2-allylanilines from allylic alcohols
由: Chen, Ke, et al.
出版: (2013)

Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
由: Ding, Feiqing, et al.
出版: (2013)

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct
由: Liu, Richard, et al.
出版: (2020)

Palladium-catalyzed allylic fluorination.
由: Hollingworth, C, et al.
出版: (2011)

Palladium-catalyzed allylic alkylation of enamides and allylic acetates
由: Lim, Juan Mei
出版: (2012)

Reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols
由: Xie, Peizhong, et al.
出版: (2022)

Catalytic enantioselective synthesis of naturally occurring butenolides via hetero-allylic alkylation and ring closing metathesis.
由: Mao, B, et al.
出版: (2011)

Lead-mediated highly diastereoselective allylation of aldehydes with cyclic allylic halides
由: Cheng, Bu-Qing, et al.
出版: (2021)

Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles
由: Knippel, James Levi, et al.
出版: (2022)

Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles
由: Knippel, James Levi, et al.
出版: (2022)

Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
由: Hodgson, D, et al.
出版: (1996)

Enantioselective arylation and vinylation of allylic bromides catalyzed by guanidinium and copper(I) salt
由: Jiang, Huan
出版: (2018)

Allylation of lactol in water
由: Zheng, Mengxue, et al.
出版: (2025)

HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT
由: Hodgson, D, et al.
出版: (1994)

Iron-mediated highly diastereoselective allylation of carbonyl compounds with cyclic allylic halides
由: Liu, Xuan-Yu, et al.
出版: (2021)

One-pot and unsymmetrical bis-allylation of malononitrile with conjugated dienes and allylic alcohols
由: Gao, Wenxiu, et al.
出版: (2023)

The antioxidant properties of garlic compounds: allyl cysteine, alliin, allicin, and allyl aisulfide
由: Chung, Lip Yong
出版: (2006)