Glycosylation catalyzed by a chiral Bronsted acid.

The use of a chiral Brønsted acid catalyst for the activation of trichloroacetimidate glycosyl donors has been demonstrated for the first time. In toluene the chirality of the acid catalyst is seen to influence the stereochemical outcome of the glycosylation processes, hinting that perhaps diastereo...

Полное описание

Библиографические подробности
Главные авторы: Cox, D, Smith, M, Fairbanks, A
Формат: Journal article
Язык:English
Опубликовано: 2010