Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts
Transition metal imido compounds having the general formula [(L) nM(NR)] [where (L) n is a supporting ligand or ligand set, and R typically is alkyl or aryl] have been known for nearly 50 years, and during the last two decades have been the focus of...
| 主要な著者: | , |
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| フォーマット: | Journal article |
| 言語: | English |
| 出版事項: |
2005
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| _version_ | 1826280973441957888 |
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| author | Bolton, P Mountford, P |
| author_facet | Bolton, P Mountford, P |
| author_sort | Bolton, P |
| collection | OXFORD |
| description | Transition metal imido compounds having the general formula [(L) nM(NR)] [where (L) n is a supporting ligand or ligand set, and R typically is alkyl or aryl] have been known for nearly 50 years, and during the last two decades have been the focus of considerable attention. Relatively recently their potential application in the Ziegler-Natta polymerisation of olefins has been realised. In this contribution we review the Ziegler-Natta polymerisation of olefins by transition metal imido compounds. A general introduction to homogeneous Ziegler-Natta olefin polymerisation and key aspects of transition metal imido chemistry is given, followed by a short description of a related imido-based polymerisation process, namely ring-opening olefin metathesis polymerisation catalysed by imido-supported molybdenum and tungsten alkylidenes. A summary of the "design principles" that have been employed in the development of certain imido-based Ziegler-Natta catalysts is presented, followed by a comprehensive survey of the literature in the title area. © 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T00:21:47Z |
| format | Journal article |
| id | oxford-uuid:7cccb0a0-6ba7-4c97-a9e2-97cd7c3f1e7d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:21:47Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:7cccb0a0-6ba7-4c97-a9e2-97cd7c3f1e7d2022-03-26T20:59:19ZTransition metal imido compounds as Ziegler-Natta olefin polymerisation catalystsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7cccb0a0-6ba7-4c97-a9e2-97cd7c3f1e7dEnglishSymplectic Elements at Oxford2005Bolton, PMountford, PTransition metal imido compounds having the general formula [(L) nM(NR)] [where (L) n is a supporting ligand or ligand set, and R typically is alkyl or aryl] have been known for nearly 50 years, and during the last two decades have been the focus of considerable attention. Relatively recently their potential application in the Ziegler-Natta polymerisation of olefins has been realised. In this contribution we review the Ziegler-Natta polymerisation of olefins by transition metal imido compounds. A general introduction to homogeneous Ziegler-Natta olefin polymerisation and key aspects of transition metal imido chemistry is given, followed by a short description of a related imido-based polymerisation process, namely ring-opening olefin metathesis polymerisation catalysed by imido-supported molybdenum and tungsten alkylidenes. A summary of the "design principles" that have been employed in the development of certain imido-based Ziegler-Natta catalysts is presented, followed by a comprehensive survey of the literature in the title area. © 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Bolton, P Mountford, P Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title | Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title_full | Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title_fullStr | Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title_full_unstemmed | Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title_short | Transition metal imido compounds as Ziegler-Natta olefin polymerisation catalysts |
| title_sort | transition metal imido compounds as ziegler natta olefin polymerisation catalysts |
| work_keys_str_mv | AT boltonp transitionmetalimidocompoundsaszieglernattaolefinpolymerisationcatalysts AT mountfordp transitionmetalimidocompoundsaszieglernattaolefinpolymerisationcatalysts |