The cyanide ligands of [FeFe] hydrogenase: pulse EPR studies of (13)C and (15)N-labeled H-cluster.

The cyanide ligands of [FeFe] hydrogenase: pulse EPR studies of (13)C and (15)N-labeled H-cluster.

The two cyanide ligands in the assembled cluster of [FeFe] hydrogenase originate from exogenous l-tyrosine. Using selectively labeled tyrosine substrates, the cyanides were isotopically labeled via a recently developed in vitro maturation procedure allowing advanced electron paramagnetic resonance t...

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Bibliographic Details
Main Authors:	Myers, W, Stich, T, Suess, D, Kuchenreuther, J, Swartz, JR, Britt, R
Format:	Journal article
Language:	English
Published:	American Chemical Society 2014

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