Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation.
[Rh(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(I) cation.
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2010
|
| _version_ | 1797077776773152768 |
|---|---|
| author | Sewell, L Chaplin, AB Abdalla, J Weller, A |
| author_facet | Sewell, L Chaplin, AB Abdalla, J Weller, A |
| author_sort | Sewell, L |
| collection | OXFORD |
| description | [Rh(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(I) cation. |
| first_indexed | 2024-03-07T00:22:51Z |
| format | Journal article |
| id | oxford-uuid:7d21d5e6-b7b6-4c25-9bc2-90debcd74f57 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:22:51Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:7d21d5e6-b7b6-4c25-9bc2-90debcd74f572022-03-26T21:01:34ZReversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7d21d5e6-b7b6-4c25-9bc2-90debcd74f57EnglishSymplectic Elements at Oxford2010Sewell, LChaplin, ABAbdalla, JWeller, A[Rh(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(I) cation. |
| spellingShingle | Sewell, L Chaplin, AB Abdalla, J Weller, A Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title | Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title_full | Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title_fullStr | Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title_full_unstemmed | Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title_short | Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. |
| title_sort | reversible c h activation of a p t bu i bu2 ligand to reveal a masked 12 electron rh pr3 2 cation |
| work_keys_str_mv | AT sewelll reversiblechactivationofaptbuibu2ligandtorevealamasked12electronrhpr32cation AT chaplinab reversiblechactivationofaptbuibu2ligandtorevealamasked12electronrhpr32cation AT abdallaj reversiblechactivationofaptbuibu2ligandtorevealamasked12electronrhpr32cation AT wellera reversiblechactivationofaptbuibu2ligandtorevealamasked12electronrhpr32cation |