Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide.
A novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radi...
| 主要な著者: | , , , , |
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| フォーマット: | Journal article |
| 言語: | English |
| 出版事項: |
2007
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| _version_ | 1826281156594630656 |
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| author | Teare, H Robins, E Arstad, E Luthra, S Gouverneur, V |
| author_facet | Teare, H Robins, E Arstad, E Luthra, S Gouverneur, V |
| author_sort | Teare, H |
| collection | OXFORD |
| description | A novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D3 has also been completed with success. |
| first_indexed | 2024-03-07T00:24:34Z |
| format | Journal article |
| id | oxford-uuid:7db2a4c6-d2c6-42ef-8e7a-dfad8a35aaee |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:24:34Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:7db2a4c6-d2c6-42ef-8e7a-dfad8a35aaee2022-03-26T21:05:16ZSynthesis and reactivity of [18F]-N-fluorobenzenesulfonimide.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7db2a4c6-d2c6-42ef-8e7a-dfad8a35aaeeEnglishSymplectic Elements at Oxford2007Teare, HRobins, EArstad, ELuthra, SGouverneur, VA novel [18F]NF reagent and two novel radiochemical transformations have been developed: [18F]NFSi has been prepared from sodium dibenzenesulfonimide and reacted in the presence of silyl enol ethers and allylsilanes to deliver labelled fluorinated ketones and allylic fluorides respectively; the radiosynthesis of the fluorinated A ring of vitamin D3 has also been completed with success. |
| spellingShingle | Teare, H Robins, E Arstad, E Luthra, S Gouverneur, V Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title_full | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title_fullStr | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title_full_unstemmed | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title_short | Synthesis and reactivity of [18F]-N-fluorobenzenesulfonimide. |
| title_sort | synthesis and reactivity of 18f n fluorobenzenesulfonimide |
| work_keys_str_mv | AT teareh synthesisandreactivityof18fnfluorobenzenesulfonimide AT robinse synthesisandreactivityof18fnfluorobenzenesulfonimide AT arstade synthesisandreactivityof18fnfluorobenzenesulfonimide AT luthras synthesisandreactivityof18fnfluorobenzenesulfonimide AT gouverneurv synthesisandreactivityof18fnfluorobenzenesulfonimide |