Isotopic polymorphism in pyridine.
Not so simple: It is normally assumed that deuteration has only a minor effect on the stabilities of crystal structures. This assumption is wrong for pyridine. A low-temperature polymorph exists for [D5]pyridine, but not for [H5]pyridine, which adds a further twist to the already unusual structural...
| Հիմնական հեղինակներ: | , , , , , , , , , , |
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| Ձևաչափ: | Journal article |
| Լեզու: | English |
| Հրապարակվել է: |
2009
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| _version_ | 1826281187286450176 |
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| author | Crawford, S Kirchner, M Bläser, D Boese, R David, W Dawson, A Gehrke, A Ibberson, R Marshall, W Parsons, S Yamamuro, O |
| author_facet | Crawford, S Kirchner, M Bläser, D Boese, R David, W Dawson, A Gehrke, A Ibberson, R Marshall, W Parsons, S Yamamuro, O |
| author_sort | Crawford, S |
| collection | OXFORD |
| description | Not so simple: It is normally assumed that deuteration has only a minor effect on the stabilities of crystal structures. This assumption is wrong for pyridine. A low-temperature polymorph exists for [D5]pyridine, but not for [H5]pyridine, which adds a further twist to the already unusual structural chemistry of one of the simplest and most familiar laboratory chemicals. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T00:25:02Z |
| format | Journal article |
| id | oxford-uuid:7dda6426-3b78-4f38-87b8-f63ed5c97cf4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:25:02Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:7dda6426-3b78-4f38-87b8-f63ed5c97cf42022-03-26T21:06:28ZIsotopic polymorphism in pyridine.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7dda6426-3b78-4f38-87b8-f63ed5c97cf4EnglishSymplectic Elements at Oxford2009Crawford, SKirchner, MBläser, DBoese, RDavid, WDawson, AGehrke, AIbberson, RMarshall, WParsons, SYamamuro, ONot so simple: It is normally assumed that deuteration has only a minor effect on the stabilities of crystal structures. This assumption is wrong for pyridine. A low-temperature polymorph exists for [D5]pyridine, but not for [H5]pyridine, which adds a further twist to the already unusual structural chemistry of one of the simplest and most familiar laboratory chemicals. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Crawford, S Kirchner, M Bläser, D Boese, R David, W Dawson, A Gehrke, A Ibberson, R Marshall, W Parsons, S Yamamuro, O Isotopic polymorphism in pyridine. |
| title | Isotopic polymorphism in pyridine. |
| title_full | Isotopic polymorphism in pyridine. |
| title_fullStr | Isotopic polymorphism in pyridine. |
| title_full_unstemmed | Isotopic polymorphism in pyridine. |
| title_short | Isotopic polymorphism in pyridine. |
| title_sort | isotopic polymorphism in pyridine |
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