VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS

Vibrational excitation of SF6 molecules in collisions with He atoms is studied using a vibrational close-coupling, rotational infinite-order-sudden method of calculation. Integral and differential cross sections for excitation of the triply degenerate ν6 and ν5 vibrational modes of SF6 are reported...

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Main Author: Clary, D
Format: Journal article
Language:English
Published: 1982
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author Clary, D
author_facet Clary, D
author_sort Clary, D
collection OXFORD
description Vibrational excitation of SF6 molecules in collisions with He atoms is studied using a vibrational close-coupling, rotational infinite-order-sudden method of calculation. Integral and differential cross sections for excitation of the triply degenerate ν6 and ν5 vibrational modes of SF6 are reported for thermal collisional energies. Excitation of the ν6 mode is found to be particularly efficieny. The cross sections are much larger than those calculated previously for the excitation of the bending mode in the He + CO2 system. The differential cross sections are backward peaked. © 1982.
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spelling oxford-uuid:7ec7add6-0d9a-4a98-820d-ba9e4567ad022022-03-26T21:12:20ZVIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7ec7add6-0d9a-4a98-820d-ba9e4567ad02EnglishSymplectic Elements at Oxford1982Clary, DVibrational excitation of SF6 molecules in collisions with He atoms is studied using a vibrational close-coupling, rotational infinite-order-sudden method of calculation. Integral and differential cross sections for excitation of the triply degenerate ν6 and ν5 vibrational modes of SF6 are reported for thermal collisional energies. Excitation of the ν6 mode is found to be particularly efficieny. The cross sections are much larger than those calculated previously for the excitation of the bending mode in the He + CO2 system. The differential cross sections are backward peaked. © 1982.
spellingShingle Clary, D
VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title_full VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title_fullStr VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title_full_unstemmed VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title_short VIBRATIONAL-EXCITATION OF SF6 IN COLLISIONS WITH HE ATOMS
title_sort vibrational excitation of sf6 in collisions with he atoms
work_keys_str_mv AT claryd vibrationalexcitationofsf6incollisionswithheatoms