Push–pull quinoidal porphyrins

A family of push–pull quinoidal porphyrin monomers has been prepared from a meso-formyl porphyrin by bromination, thioacetal formation, palladium-catalyzed coupling with malononitrile and oxidation with DDQ. Attempts at extending this synthesis to a push–pull quinoidal/cumulenic porphyrin dimer were...

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Autori principali: Smith, M, Blake, I, Clegg, W, Anderson, H
Natura: Journal article
Lingua:English
Pubblicazione: Royal Society of Chemistry 2018

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