Carbohydrate-derived amino-alcohol ligands for asymmetric alkynylation of aldehydes.
[reaction: see text] Conformationally restricted amino alcohols based on carbohydrate scaffolds provide flexible and fine-tuneable libraries that greatly expand the range of ligands available in the Zn(OTf)(2)-mediated addition of alkynes to aldehydes, in some cases with very high stereoselectivitie...
Glavni autori: | Emmerson, D, Hems, W, Davis, B |
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Format: | Journal article |
Jezik: | English |
Izdano: |
2006
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Slični predmeti
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Carbohydrate-derived aminoalcohol ligands for asymmetric Reformatsky reactions
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