Influence of the diffuse double layer on steady-state voltammetry

Influence of the diffuse double layer on steady-state voltammetry

The influence of the diffuse double layer on the passage of Faradaic current is investigated for steady-state voltammetry. Both mathematical analysis and numerical solution with the Nernst-Planck-Poisson equations are employed. We report a comprehensive study of the effects of reactant charge, elect...

Πλήρης περιγραφή

Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς:	Dickinson, E, Compton, R
Μορφή:	Journal article
Γλώσσα:	English
Έκδοση:	2011

Παρόμοια τεκμήρια

Diffuse Double Layer at Nanoelectrodes
ανά: Dickinson, E, κ.ά.
Έκδοση: (2009)

Are steady state diffusion layer thicknesses potential independent?
ανά: Streeter, I, κ.ά.
Έκδοση: (2008)

Modelling the steady state voltammetry of a single spherical nanoparticle on a surface
ανά: Ward, K, κ.ά.
Έκδοση: (2012)

A data analysis service for steady-state voltammetry via the World Wide Web
ανά: Alden, J, κ.ά.
Έκδοση: (1998)

Finite difference simulations of steady-state voltammetry at the wall-jet electrode. Effects of radial diffusion and working curves for common electrochemical mechanisms
ανά: Alden, J, κ.ά.
Έκδοση: (1999)

Voltammetry of porous layers: Staircase vs analog voltammetry
ανά: Ban, Z, κ.ά.
Έκδοση: (2016)

Cyclic Voltammetry Part 2: Surface Adsorption, Electric Double Layer, and Diffusion Layer
ανά: Hirohisa YAMADA, κ.ά.
Έκδοση: (2022-10-01)

Solution of ring electrode problems in spherical coordinates: An application to near-steady-state linear sweep voltammetry
ανά: Svir, I, κ.ά.
Έκδοση: (2003)

Gold ultra-microelectrode arrays: application to the steady-state voltammetry of hydroxide ion in aqueous solution.
ανά: Ordeig, O, κ.ά.
Έκδοση: (2006)

Electrochemical random-walk theory Probing voltammetry with small numbers of molecules: Stochastic versus statistical (Fickian) diffusion
ανά: Cutress, I, κ.ά.
Έκδοση: (2011)

Fickian diffusion constrained on spherical surfaces: voltammetry.
ανά: Thompson, M, κ.ά.
Έκδοση: (2006)

Microwave enhanced electrochemistry: mass transport effects and steady state voltammetry in the sub-millisecond time domain
ανά: Sur, UK, κ.ά.
Έκδοση: (2004)

Steady-state voltammetry at a microdisc electrode in the absence of excess supporting electrolyte for reversible, quasi-reversible and irreversible electrode kinetics.
ανά: Belding, SR, κ.ά.
Έκδοση: (2012)

How well does simple RC circuit analysis describe diffuse double layer capacitance at smooth micro- and nanoelectrodes?
ανά: Dickinson, E, κ.ά.
Έκδοση: (2011)

Voltammetry in the presence of ultrasound: The limit of acoustic streaming induced diffusion layer thinning and the effect of solvent viscosity
ανά: Marken, F, κ.ά.
Έκδοση: (1996)

A comparison of the time scales accessible and kinetic discrimination obtainable using steady-state voltammetry at common hydrodynamic and microelectrode geometries
ανά: Alden, J, κ.ά.
Έκδοση: (1999)

The zero-field approximation for weakly supported voltammetry: A critical evaluation
ανά: Dickinson, E, κ.ά.
Έκδοση: (2010)

On the estimation of the diffuse double layer of carbon nanotubes using classical theory: curvature effects on the Gouy-Chapman limit
ανά: Henstridge, M, κ.ά.
Έκδοση: (2010)

On the estimation of the diffuse double layer of carbon nanotubes using classical theory: Curvature effects on the Gouy-Chapman limit
ανά: Henstridge, M, κ.ά.
Έκδοση: (2010)

Hydrodynamic voltammetry with channel microband electrodes: Axial diffusion effects
ανά: Alden, J, κ.ά.
Έκδοση: (1996)

Reciprocal Sum Expression for Steady-state Kinetics —Enzyme Reactions and Voltammetry—
ανά: Yuko YOKOYAMA, κ.ά.
Έκδοση: (2022-07-01)

Mass transport to and within porous electrodes. Linear sweep voltammetry and the effects of pore size: The prediction of double peaks for a single electrode process
ανά: Henstridge, M, κ.ά.
Έκδοση: (2012)

Analytical approach to the transient and steady-state Cyclic Voltammetry of non-reversible electrode processes. Defining the transition from macro to microelectrodes
ανά: Gonzalez, J, κ.ά.
Έκδοση: (2016)

Chronoamperometry and cyclic voltammetry at conical electrodes, microelectrodes, and electrode arrays: theory.
ανά: Dickinson, E, κ.ά.
Έκδοση: (2008)

Influence of electrode roughness on cyclic voltammetry
ανά: Menshykau, D, κ.ά.
Έκδοση: (2008)

Steady state voltammetry at non-uniformly accessible electrodes: a study of Tafel plots for microdisc and tubular flow electrodes in the reversible and irreversible limits of electron transfer.
ανά: Streeter, I, κ.ά.
Έκδοση: (2007)

The Influence of Electrode Porosity on Diffusional Cyclic Voltammetry
ανά: Menshykau, D, κ.ά.
Έκδοση: (2008)

Diffusional Cyclic Voltammetry at Electrodes Modified with Random Distributions of Electrocatalytic Nanoparticles: Theory
ανά: Belding, SR, κ.ά.
Έκδοση: (2009)

Analytical theoretical approach to the transient and steady state voltammetric response of reaction mechanisms. Linear diffusion and reaction layers at micro- and submicroelectrodes of arbitrary geometry
ανά: Molina, A, κ.ά.
Έκδοση: (2016)

Understanding voltammetry /
ανά: 200074 Compton, R. G., κ.ά.
Έκδοση: (c201)

Can cyclic voltammetry at microdisc electrodes be approximately described by one-dimensional diffusion?
ανά: Alden, J, κ.ά.
Έκδοση: (1997)

Variable-temperature microelectrode voltammetry: Application to diffusion coefficients and electrode reaction mechanisms
ανά: Jacob, SR, κ.ά.
Έκδοση: (1999)

Understanding voltammetry /
ανά: 231637 Compton, Richard G., κ.ά.
Έκδοση: (2007)

Hydrodynamic microelectrode voltammetry
ανά: Rees, N, κ.ά.
Έκδοση: (2008)

Thin-layer vs. semi-infinite diffusion in cylindrical pores: A basis for delineating Fickian transport to identify nano-confinement effects in voltammetry
ανά: Ward, K, κ.ά.
Έκδοση: (2013)

Channel electrode voltammetry: Thin-layer effects and the shape of quasi-reversible current-voltage curves
ανά: Compton, R, κ.ά.
Έκδοση: (1992)

Enhancing selectivity in stripping voltammetry by different adsorption behaviors: the use of nanostructured Mg-Al-layered double hydroxides to detect Cd(II).
ανά: Xu, R, κ.ά.
Έκδοση: (2013)

Laser-activated voltammetry: measurement of the diffusion coefficients of electropassivating species. Application to pyrrole and phenol in aqueous solution
ανά: Fulian, Q, κ.ά.
Έκδοση: (2000)

Influence of Electrode Roughness on Stripping Voltammetry: Mathematical Modeling and Numerical Simulation
ανά: Menshykau, D, κ.ά.
Έκδοση: (2009)

Electrode modification using porous layers. Maximising the analytical response by choosing the most suitable voltammetry: Differential Pulse vs Square Wave vs Linear sweep voltammetry
ανά: Laborda, E, κ.ά.
Έκδοση: (2012)