ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS
The electron spin relaxation times T 1 and T 2 of lithium-6- and lithium-7-methylamine solutions have been measured by electron spin-echo techniques over the temperature range 200-260 K. T 1 and T 2 are n...
| Main Authors: | , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
1984
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| _version_ | 1826281831075414016 |
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| author | Page, C Millhauser, G Edwards, P Freed, J Sienko, M |
| author_facet | Page, C Millhauser, G Edwards, P Freed, J Sienko, M |
| author_sort | Page, C |
| collection | OXFORD |
| description | The electron spin relaxation times T 1 and T 2 of lithium-6- and lithium-7-methylamine solutions have been measured by electron spin-echo techniques over the temperature range 200-260 K. T 1 and T 2 are not equal in the concentration range studied (0.1-5.0 MPM); their values differ most at low concentrations and low temperatures. No significant lithium isotope effect is observed. The accepted relaxation mechanism for dilute metal-ammonia solutions (motional modulation of the electron- 14N hyperfine interaction) cannot alone account for the observed relaxation times in lithium-methylamine solutions. © 1984 American Chemical Society. |
| first_indexed | 2024-03-07T00:34:43Z |
| format | Journal article |
| id | oxford-uuid:8101946a-101d-49db-88f5-30a40a5f34c9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:34:43Z |
| publishDate | 1984 |
| record_format | dspace |
| spelling | oxford-uuid:8101946a-101d-49db-88f5-30a40a5f34c92022-03-26T21:27:20ZELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONSJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8101946a-101d-49db-88f5-30a40a5f34c9EnglishSymplectic Elements at Oxford1984Page, CMillhauser, GEdwards, PFreed, JSienko, MThe electron spin relaxation times T 1 and T 2 of lithium-6- and lithium-7-methylamine solutions have been measured by electron spin-echo techniques over the temperature range 200-260 K. T 1 and T 2 are not equal in the concentration range studied (0.1-5.0 MPM); their values differ most at low concentrations and low temperatures. No significant lithium isotope effect is observed. The accepted relaxation mechanism for dilute metal-ammonia solutions (motional modulation of the electron- 14N hyperfine interaction) cannot alone account for the observed relaxation times in lithium-methylamine solutions. © 1984 American Chemical Society. |
| spellingShingle | Page, C Millhauser, G Edwards, P Freed, J Sienko, M ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title | ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title_full | ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title_fullStr | ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title_full_unstemmed | ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title_short | ELECTRON SPIN-ECHO STUDIES OF RELAXATION-TIMES IN LITHIUM METHYLAMINE SOLUTIONS |
| title_sort | electron spin echo studies of relaxation times in lithium methylamine solutions |
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