Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols

The asymmetric synthesis of 4-substituted cis-4-(hydroxymethyl)cyclopent-2-en-1-ols 3 (R = alkyl, benzyloxymethyl) via highly enantioselective rearrangement of 3-substituted cis-6-oxabicyclo[3.1.0]hexane-3-methanols 1 (R = alkyl, benzyloxymethyl) is described.

Bibliographic Details
Main Authors: Hodgson, D, Gibbs, A
Format: Journal article
Language:English
Published: 1996
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author Hodgson, D
Gibbs, A
author_facet Hodgson, D
Gibbs, A
author_sort Hodgson, D
collection OXFORD
description The asymmetric synthesis of 4-substituted cis-4-(hydroxymethyl)cyclopent-2-en-1-ols 3 (R = alkyl, benzyloxymethyl) via highly enantioselective rearrangement of 3-substituted cis-6-oxabicyclo[3.1.0]hexane-3-methanols 1 (R = alkyl, benzyloxymethyl) is described.
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spelling oxford-uuid:810aaf74-5288-4327-aba5-cc581e856ae62022-03-26T21:27:35ZHighly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcoholsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:810aaf74-5288-4327-aba5-cc581e856ae6EnglishSymplectic Elements at Oxford1996Hodgson, DGibbs, AThe asymmetric synthesis of 4-substituted cis-4-(hydroxymethyl)cyclopent-2-en-1-ols 3 (R = alkyl, benzyloxymethyl) via highly enantioselective rearrangement of 3-substituted cis-6-oxabicyclo[3.1.0]hexane-3-methanols 1 (R = alkyl, benzyloxymethyl) is described.
spellingShingle Hodgson, D
Gibbs, A
Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title_full Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title_fullStr Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title_full_unstemmed Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title_short Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
title_sort highly enantioselective rearrangement of quaternary carbon containing meso epoxides to allylic alcohols
work_keys_str_mv AT hodgsond highlyenantioselectiverearrangementofquaternarycarboncontainingmesoepoxidestoallylicalcohols
AT gibbsa highlyenantioselectiverearrangementofquaternarycarboncontainingmesoepoxidestoallylicalcohols