Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide.
The first cationic main group tetrahydroborate complexes are reported. [Ca(BH(4))(THF)(5)][BPh(4)] and the charge neutral (Tp((t)Bu,Me))Ca(BH(4))(THF) are initiators for the living ring opening polymerization of rac-lactide, the latter producing PLA with high levels of heterotactic enrichment. These...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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2011
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| _version_ | 1826281874180276224 |
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| author | Cushion, MG Mountford, P |
| author_facet | Cushion, MG Mountford, P |
| author_sort | Cushion, MG |
| collection | OXFORD |
| description | The first cationic main group tetrahydroborate complexes are reported. [Ca(BH(4))(THF)(5)][BPh(4)] and the charge neutral (Tp((t)Bu,Me))Ca(BH(4))(THF) are initiators for the living ring opening polymerization of rac-lactide, the latter producing PLA with high levels of heterotactic enrichment. These represent a new class of ROP initiators for main group metals. |
| first_indexed | 2024-03-07T00:35:22Z |
| format | Journal article |
| id | oxford-uuid:8135dc90-6f99-4852-ab6e-3e80171a9a86 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:35:22Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:8135dc90-6f99-4852-ab6e-3e80171a9a862022-03-26T21:28:53ZCationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8135dc90-6f99-4852-ab6e-3e80171a9a86EnglishSymplectic Elements at Oxford2011Cushion, MGMountford, PThe first cationic main group tetrahydroborate complexes are reported. [Ca(BH(4))(THF)(5)][BPh(4)] and the charge neutral (Tp((t)Bu,Me))Ca(BH(4))(THF) are initiators for the living ring opening polymerization of rac-lactide, the latter producing PLA with high levels of heterotactic enrichment. These represent a new class of ROP initiators for main group metals. |
| spellingShingle | Cushion, MG Mountford, P Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title | Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title_full | Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title_fullStr | Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title_full_unstemmed | Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title_short | Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide. |
| title_sort | cationic and charge neutral calcium tetrahydroborate complexes and their use in the controlled ring opening polymerisation of rac lactide |
| work_keys_str_mv | AT cushionmg cationicandchargeneutralcalciumtetrahydroboratecomplexesandtheiruseinthecontrolledringopeningpolymerisationofraclactide AT mountfordp cationicandchargeneutralcalciumtetrahydroboratecomplexesandtheiruseinthecontrolledringopeningpolymerisationofraclactide |