EXPERIMENTAL AND RRKM MODELING STUDY OF THE CH3+H AND CH3+D REACTIONS

Rate coefficients for the reactions CH3 + H and CH3 + D are presented over the temperature ranges 300 ≤ T/K ≤ 600 and 289 ≤ T/K ≤ 400, respectively. The laser flash photolysis (193 nm) of acetone or acetone/N2O/D2 mixtures was employed to generate CH3 and H or CH3 and D, respectively, and the time d...

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Bibliographic Details
Main Authors: Brouard, M, Macpherson, M, Pilling, M
Format: Journal article
Language:English
Published: 1989