3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,...
Title full: 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol, 1,4-dideoxy-i,4-imino-d-lyxitol, 2S,3S,4R-3,4-dihydroxyproline and (1S,2R,8S,8aR)-1,2,8-trihydroxyoctahyd...
| প্রধান লেখক: | , , , , , |
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| বিন্যাস: | Journal article |
| ভাষা: | English |
| প্রকাশিত: |
1987
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| _version_ | 1826281900973490176 |
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| author | Fleet, G Peach, J Smith, P Austin, G Baird, P Watkin, D |
| author_facet | Fleet, G Peach, J Smith, P Austin, G Baird, P Watkin, D |
| author_sort | Fleet, G |
| collection | OXFORD |
| description | Title full: 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol, 1,4-dideoxy-i,4-imino-d-lyxitol, 2S,3S,4R-3,4-dihydroxyproline and (1S,2R,8S,8aR)-1,2,8-trihydroxyoctahydroindolizine [8-epi swainsonine]. X-ray crystal structure of (1S,2R,8S,8aR)-1,2,8-trihydroxy-5-oxo octahydroindolizine. An efficient synthesis of the p-toluenesulphonate salt of 3,6-dideoxy-3,6-imino 1,2-0-isopropylidene-α-D-glucofuranose (1) from glucose is reported; the potential of (1) in making hydroxylated pyrrolidines is illustrated by the preparation of 1,4-dideoxy-1,4-imino-L-gulitol, 1,4-dideoxy-1,4-imino-D-lyxitol (a powerful α galactosidase inhibitor), 2S,3S,4R-3,4-dihydroxyproline and (1S,2R,8S,8aR)-1,2,6 trihydroxyoctahydroindolizine [8-epi-Swainsonine]. An X-ray crystal structure of (1S,2R,83,8aR)-1,2,8-trihydroxy-5-oxo-octahydroindolizine is reported. © 1987. |
| first_indexed | 2024-03-07T00:35:46Z |
| format | Journal article |
| id | oxford-uuid:81576b4e-a5d7-48c8-a61a-ad0cb998a0ff |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:35:46Z |
| publishDate | 1987 |
| record_format | dspace |
| spelling | oxford-uuid:81576b4e-a5d7-48c8-a61a-ad0cb998a0ff2022-03-26T21:29:43Z3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,...Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:81576b4e-a5d7-48c8-a61a-ad0cb998a0ffEnglishSymplectic Elements at Oxford1987Fleet, GPeach, JSmith, PAustin, GBaird, PWatkin, DTitle full: 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol, 1,4-dideoxy-i,4-imino-d-lyxitol, 2S,3S,4R-3,4-dihydroxyproline and (1S,2R,8S,8aR)-1,2,8-trihydroxyoctahydroindolizine [8-epi swainsonine]. X-ray crystal structure of (1S,2R,8S,8aR)-1,2,8-trihydroxy-5-oxo octahydroindolizine. An efficient synthesis of the p-toluenesulphonate salt of 3,6-dideoxy-3,6-imino 1,2-0-isopropylidene-α-D-glucofuranose (1) from glucose is reported; the potential of (1) in making hydroxylated pyrrolidines is illustrated by the preparation of 1,4-dideoxy-1,4-imino-L-gulitol, 1,4-dideoxy-1,4-imino-D-lyxitol (a powerful α galactosidase inhibitor), 2S,3S,4R-3,4-dihydroxyproline and (1S,2R,8S,8aR)-1,2,6 trihydroxyoctahydroindolizine [8-epi-Swainsonine]. An X-ray crystal structure of (1S,2R,83,8aR)-1,2,8-trihydroxy-5-oxo-octahydroindolizine is reported. © 1987. |
| spellingShingle | Fleet, G Peach, J Smith, P Austin, G Baird, P Watkin, D 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title | 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title_full | 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title_fullStr | 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title_full_unstemmed | 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title_short | 3,6-dideoxy-3,6-imino-1,2-o-isopropylidene-α-d-glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines; synthesis of 1,4 dideoxy-1,4-imino-l-gulitol,... |
| title_sort | 3 6 dideoxy 3 6 imino 1 2 o isopropylidene α d glucofuranose as a divergent intermediate for the synthesis of hydroxylated pyrrolidines synthesis of 1 4 dideoxy 1 4 imino l gulitol |
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