A conjugated thiophene-based rotaxane: synthesis, spectroscopy, and modeling.
A dithiophene rotaxane 1 subsetbeta-CD and its shape-persistent corresponding dumbbell 1 were synthesized and fully characterized. 2D NOESY experiments, supported by molecular dynamics calculations, revealed a very mobile macrocycle (beta-CD). Steady-state and time-resolved photoluminescence experim...
| Main Authors: | , , , , , , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
2010
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