Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane.
The first example of utilizing halogen-bonding anion recognition to facilitate molecular motion in an interlocked structure is described. A halogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttling of the macrocycle component from the hydrogen-bonding s...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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Wiley
2014
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| _version_ | 1826281952225787904 |
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| author | Caballero, A Swan, L Zapata, F Beer, P |
| author_facet | Caballero, A Swan, L Zapata, F Beer, P |
| author_sort | Caballero, A |
| collection | OXFORD |
| description | The first example of utilizing halogen-bonding anion recognition to facilitate molecular motion in an interlocked structure is described. A halogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttling of the macrocycle component from the hydrogen-bonding station to the halogen-bonding station upon iodide recognition. In contrast, chloride-anion binding reinforces the macrocycle to reside at the hydrogen-bonding station. |
| first_indexed | 2024-03-07T00:36:32Z |
| format | Journal article |
| id | oxford-uuid:819e12a5-a5a1-4b74-a118-abd3e5415f57 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:36:32Z |
| publishDate | 2014 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:819e12a5-a5a1-4b74-a118-abd3e5415f572022-03-26T21:31:24ZIodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:819e12a5-a5a1-4b74-a118-abd3e5415f57EnglishSymplectic Elements at OxfordWiley2014Caballero, ASwan, LZapata, FBeer, PThe first example of utilizing halogen-bonding anion recognition to facilitate molecular motion in an interlocked structure is described. A halogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttling of the macrocycle component from the hydrogen-bonding station to the halogen-bonding station upon iodide recognition. In contrast, chloride-anion binding reinforces the macrocycle to reside at the hydrogen-bonding station. |
| spellingShingle | Caballero, A Swan, L Zapata, F Beer, P Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title | Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title_full | Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title_fullStr | Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title_full_unstemmed | Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title_short | Iodide-induced shuttling of a halogen- and hydrogen-bonding two-station rotaxane. |
| title_sort | iodide induced shuttling of a halogen and hydrogen bonding two station rotaxane |
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