Sub-10 fs Time-Resolved Vibronic Optical Microscopy
We introduce femtosecond wide-field transient absorption microscopy combining sub-10 fs pump and probe pulses covering the complete visible (500–650 nm) and near-infrared (650–950 nm) spectrum with diffraction-limited optical resolution. We demonstrate the capabilities of our system by reporting the...
| المؤلفون الرئيسيون: | , , , , , , , , |
|---|---|
| التنسيق: | Journal article |
| منشور في: |
American Chemical Society
2016
|
| _version_ | 1826282107023917056 |
|---|---|
| author | Schnedermann, C Lim, J Wende, T Duarte, A Ni, L Gu, Q Sadhanala, A Rao, A Kukura, P |
| author_facet | Schnedermann, C Lim, J Wende, T Duarte, A Ni, L Gu, Q Sadhanala, A Rao, A Kukura, P |
| author_sort | Schnedermann, C |
| collection | OXFORD |
| description | We introduce femtosecond wide-field transient absorption microscopy combining sub-10 fs pump and probe pulses covering the complete visible (500–650 nm) and near-infrared (650–950 nm) spectrum with diffraction-limited optical resolution. We demonstrate the capabilities of our system by reporting the spatially- and spectrally-resolved transient electronic response of MAPbI3–xClx perovskite films and reveal significant quenching of the transient bleach signal at grain boundaries. The unprecedented temporal resolution enables us to directly observe the formation of band-gap renormalization, completed in 25 fs after photoexcitation. In addition, we acquire hyperspectral Raman maps of TIPS pentacene films with sub-400 nm spatial and sub-15 cm–1 spectral resolution covering the 100–2000 cm–1 window. Our approach opens up the possibility of studying ultrafast dynamics on nanometer length and femtosecond time scales in a variety of two-dimensional and nanoscopic systems. |
| first_indexed | 2024-03-07T00:38:51Z |
| format | Journal article |
| id | oxford-uuid:825915db-5436-4a06-901b-6c56ad8a53ba |
| institution | University of Oxford |
| last_indexed | 2024-03-07T00:38:51Z |
| publishDate | 2016 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:825915db-5436-4a06-901b-6c56ad8a53ba2022-03-26T21:36:46ZSub-10 fs Time-Resolved Vibronic Optical MicroscopyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:825915db-5436-4a06-901b-6c56ad8a53baSymplectic Elements at OxfordAmerican Chemical Society2016Schnedermann, CLim, JWende, TDuarte, ANi, LGu, QSadhanala, ARao, AKukura, PWe introduce femtosecond wide-field transient absorption microscopy combining sub-10 fs pump and probe pulses covering the complete visible (500–650 nm) and near-infrared (650–950 nm) spectrum with diffraction-limited optical resolution. We demonstrate the capabilities of our system by reporting the spatially- and spectrally-resolved transient electronic response of MAPbI3–xClx perovskite films and reveal significant quenching of the transient bleach signal at grain boundaries. The unprecedented temporal resolution enables us to directly observe the formation of band-gap renormalization, completed in 25 fs after photoexcitation. In addition, we acquire hyperspectral Raman maps of TIPS pentacene films with sub-400 nm spatial and sub-15 cm–1 spectral resolution covering the 100–2000 cm–1 window. Our approach opens up the possibility of studying ultrafast dynamics on nanometer length and femtosecond time scales in a variety of two-dimensional and nanoscopic systems. |
| spellingShingle | Schnedermann, C Lim, J Wende, T Duarte, A Ni, L Gu, Q Sadhanala, A Rao, A Kukura, P Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title | Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title_full | Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title_fullStr | Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title_full_unstemmed | Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title_short | Sub-10 fs Time-Resolved Vibronic Optical Microscopy |
| title_sort | sub 10 fs time resolved vibronic optical microscopy |
| work_keys_str_mv | AT schnedermannc sub10fstimeresolvedvibronicopticalmicroscopy AT limj sub10fstimeresolvedvibronicopticalmicroscopy AT wendet sub10fstimeresolvedvibronicopticalmicroscopy AT duartea sub10fstimeresolvedvibronicopticalmicroscopy AT nil sub10fstimeresolvedvibronicopticalmicroscopy AT guq sub10fstimeresolvedvibronicopticalmicroscopy AT sadhanalaa sub10fstimeresolvedvibronicopticalmicroscopy AT raoa sub10fstimeresolvedvibronicopticalmicroscopy AT kukurap sub10fstimeresolvedvibronicopticalmicroscopy |