Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).
Solid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX(2)(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF(2)(pyrazine) exhibits unique trans doubly-bridged Cu-F(2)-Cu chains...
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Bibliographic Details
| Main Authors: |
Lapidus, S,
Manson, J,
Liu, J,
Smith, M,
Goddard, P,
Bendix, J,
Topping, C,
Singleton, J,
Dunmars, C,
Mitchell, J,
Schlueter, J |
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| Format: | Journal article
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| Language: | English |
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| Published: |
2013
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