Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).
Solid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX(2)(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF(2)(pyrazine) exhibits unique trans doubly-bridged Cu-F(2)-Cu chains...
| Main Authors: | , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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| _version_ | 1826282144048087040 |
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| author | Lapidus, S Manson, J Liu, J Smith, M Goddard, P Bendix, J Topping, C Singleton, J Dunmars, C Mitchell, J Schlueter, J |
| author_facet | Lapidus, S Manson, J Liu, J Smith, M Goddard, P Bendix, J Topping, C Singleton, J Dunmars, C Mitchell, J Schlueter, J |
| author_sort | Lapidus, S |
| collection | OXFORD |
| description | Solid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX(2)(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF(2)(pyrazine) exhibits unique trans doubly-bridged Cu-F(2)-Cu chains that provide an opportunity to quantify magnetic superexchange in an isostructural Cu-X(2)-Cu series. |
| first_indexed | 2024-03-07T00:39:24Z |
| format | Journal article |
| id | oxford-uuid:8286087b-2d02-4730-b8fa-55af90c39d3d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:39:24Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:8286087b-2d02-4730-b8fa-55af90c39d3d2022-03-26T21:38:01ZQuantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8286087b-2d02-4730-b8fa-55af90c39d3dEnglishSymplectic Elements at Oxford2013Lapidus, SManson, JLiu, JSmith, MGoddard, PBendix, JTopping, CSingleton, JDunmars, CMitchell, JSchlueter, JSolid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX(2)(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF(2)(pyrazine) exhibits unique trans doubly-bridged Cu-F(2)-Cu chains that provide an opportunity to quantify magnetic superexchange in an isostructural Cu-X(2)-Cu series. |
| spellingShingle | Lapidus, S Manson, J Liu, J Smith, M Goddard, P Bendix, J Topping, C Singleton, J Dunmars, C Mitchell, J Schlueter, J Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title | Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title_full | Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title_fullStr | Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title_full_unstemmed | Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title_short | Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine). |
| title_sort | quantifying magnetic exchange in doubly bridged cu x 2 cu x f cl br chains enabled by solid state synthesis of cuf 2 pyrazine |
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