Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).

Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).

Solid state techniques involving pressure and temperature have been used to synthesize the fluoride member of the CuX(2)(pyrazine) (X = F, Cl, Br) family of coordination polymers that cannot be crystallized by solution methods. CuF(2)(pyrazine) exhibits unique trans doubly-bridged Cu-F(2)-Cu chains...

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Bibliographic Details
Main Authors:	Lapidus, S, Manson, J, Liu, J, Smith, M, Goddard, P, Bendix, J, Topping, C, Singleton, J, Dunmars, C, Mitchell, J, Schlueter, J
Format:	Journal article
Language:	English
Published:	2013

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