Amperometric environmental phosphate sensor
We report a novel amperometric sensor for aqueous phosphate ions in freshwater systems based on the reductive square wave voltammetry of molybdate (VI) anions immobilized within a chitosan matrix deposited on a glassy carbon electrode. A sensitivity of 4.4±0.1 μA/μM was realized together with a LOD...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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American Chemical Society
2021
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| _version_ | 1797107494629146624 |
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| author | Lu, Y Li, X Li, D Compton, R |
| author_facet | Lu, Y Li, X Li, D Compton, R |
| author_sort | Lu, Y |
| collection | OXFORD |
| description | We report a novel amperometric sensor for aqueous phosphate ions in freshwater systems based on the reductive square wave voltammetry of molybdate (VI) anions immobilized within a chitosan matrix deposited on a glassy carbon electrode. A sensitivity of 4.4±0.1 μA/μM was realized together with a LOD of 0.15 μM. The sensor was insensitive to chloride and nitrate ions below threshold concentration of 1.0 mM respectively. Analytical measurements were successfully made in authentic samples of tap and pond water. |
| first_indexed | 2024-03-07T07:16:56Z |
| format | Journal article |
| id | oxford-uuid:829fe6ca-4c3c-43dd-af3f-f1c0d028378b |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:16:56Z |
| publishDate | 2021 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:829fe6ca-4c3c-43dd-af3f-f1c0d028378b2022-08-23T08:16:44ZAmperometric environmental phosphate sensorJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:829fe6ca-4c3c-43dd-af3f-f1c0d028378bEnglishSymplectic ElementsAmerican Chemical Society2021Lu, YLi, XLi, DCompton, RWe report a novel amperometric sensor for aqueous phosphate ions in freshwater systems based on the reductive square wave voltammetry of molybdate (VI) anions immobilized within a chitosan matrix deposited on a glassy carbon electrode. A sensitivity of 4.4±0.1 μA/μM was realized together with a LOD of 0.15 μM. The sensor was insensitive to chloride and nitrate ions below threshold concentration of 1.0 mM respectively. Analytical measurements were successfully made in authentic samples of tap and pond water. |
| spellingShingle | Lu, Y Li, X Li, D Compton, R Amperometric environmental phosphate sensor |
| title | Amperometric environmental phosphate sensor |
| title_full | Amperometric environmental phosphate sensor |
| title_fullStr | Amperometric environmental phosphate sensor |
| title_full_unstemmed | Amperometric environmental phosphate sensor |
| title_short | Amperometric environmental phosphate sensor |
| title_sort | amperometric environmental phosphate sensor |
| work_keys_str_mv | AT luy amperometricenvironmentalphosphatesensor AT lix amperometricenvironmentalphosphatesensor AT lid amperometricenvironmentalphosphatesensor AT comptonr amperometricenvironmentalphosphatesensor |