One-step preparation of functionalized (E)-vinylsilanes from aldehydes.

Functionalized (E)-vinylsilanes have been prepared in one step from a wide range of aldehydes, via a chromium(II)-mediated olefination with novel dihalomethylsilane reagents, in moderate to excellent yields and with excellent stereoselectivity.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Lim, D, Anderson, E
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2011