Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But 3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
The crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2 was obtained, revealing the following properties: triclinic, space group P1 with a = 13.9482(2), b = 14.7621(2), c = 18.9520(2)Å, α = 104.9195(6), β = 93.6985(7), γ = 97.1409(5)°, Z = 2, R = 0.059 and wR2 = 0.133 f...
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
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2008
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_version_ | 1797079051841568768 |
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author | Coombs, N Watkin, D Aldridge, S |
author_facet | Coombs, N Watkin, D Aldridge, S |
author_sort | Coombs, N |
collection | OXFORD |
description | The crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2 was obtained, revealing the following properties: triclinic, space group P1 with a = 13.9482(2), b = 14.7621(2), c = 18.9520(2)Å, α = 104.9195(6), β = 93.6985(7), γ = 97.1409(5)°, Z = 2, R = 0.059 and wR2 = 0.133 for all 19611 unique reflections. The In-F-In bridging unit is characterized by In-F distances of 2.1674(18) and 2.1637(18)Å and by an In-F-In angle of 171.28(11)°; each indium centre is planar three-coordinate (∑angles at indium = 360°, within the standard 3σ limit, in each case) with In-Fe distances of 2.4740(5) and 2.4760(5)Å and Fe-In-Cipso angles of 153.75(8) and 154.79(9)°. 2008 © The Japan Society for Analytical Chemistry. |
first_indexed | 2024-03-07T00:40:08Z |
format | Journal article |
id | oxford-uuid:82c169a1-1344-4d02-80c5-af9a2e6cb1e6 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T00:40:08Z |
publishDate | 2008 |
record_format | dspace |
spelling | oxford-uuid:82c169a1-1344-4d02-80c5-af9a2e6cb1e62022-03-26T21:39:37ZCrystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But 3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2 Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:82c169a1-1344-4d02-80c5-af9a2e6cb1e6EnglishSymplectic Elements at Oxford2008Coombs, NWatkin, DAldridge, SThe crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2 was obtained, revealing the following properties: triclinic, space group P1 with a = 13.9482(2), b = 14.7621(2), c = 18.9520(2)Å, α = 104.9195(6), β = 93.6985(7), γ = 97.1409(5)°, Z = 2, R = 0.059 and wR2 = 0.133 for all 19611 unique reflections. The In-F-In bridging unit is characterized by In-F distances of 2.1674(18) and 2.1637(18)Å and by an In-F-In angle of 171.28(11)°; each indium centre is planar three-coordinate (∑angles at indium = 360°, within the standard 3σ limit, in each case) with In-Fe distances of 2.4740(5) and 2.4760(5)Å and Fe-In-Cipso angles of 153.75(8) and 154.79(9)°. 2008 © The Japan Society for Analytical Chemistry. |
spellingShingle | Coombs, N Watkin, D Aldridge, S Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But 3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2 |
title | Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But
3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
|
title_full | Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But
3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
|
title_fullStr | Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But
3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
|
title_full_unstemmed | Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But
3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
|
title_short | Crystal structure of [{(η5-C5Me5)Fe(CO)2In(C6H2But
3-2,4,6)}2(μ-F)]+(BF4)-·3CH2Cl2
|
title_sort | crystal structure of η5 c5me5 fe co 2in c6h2but 3 2 4 6 2 μ f bf4 ·3ch2cl2 |
work_keys_str_mv | AT coombsn crystalstructureofē5c5me5feco2inc6h2but32462mfbf43ch2cl2 AT watkind crystalstructureofē5c5me5feco2inc6h2but32462mfbf43ch2cl2 AT aldridges crystalstructureofē5c5me5feco2inc6h2but32462mfbf43ch2cl2 |