Reconfigurable low-emissivity optical coating using ultrathin phase change materials

A method for controlling the optical properties of a solid-state film over a broad wavelength range is highly desirable and could have significant commercial impact. One such application is smart glazing technology where near-infrared solar radiation is harvested in the winter and reflected it in th...

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Main Authors: Youngblood, N, Talagrand, C, Porter, BF, Galante, CG, Kneepkens, S, Triggs, G, Sarwat, SG, Yarmolich, D, Bonilla, RS, Hosseini, P, Taylor, RA, Bhaskaran, H
Format: Journal article
Language:English
Published: American Chemical Society 2021
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author Youngblood, N
Talagrand, C
Porter, BF
Galante, CG
Kneepkens, S
Triggs, G
Sarwat, SG
Yarmolich, D
Bonilla, RS
Hosseini, P
Taylor, RA
Bhaskaran, H
author_facet Youngblood, N
Talagrand, C
Porter, BF
Galante, CG
Kneepkens, S
Triggs, G
Sarwat, SG
Yarmolich, D
Bonilla, RS
Hosseini, P
Taylor, RA
Bhaskaran, H
author_sort Youngblood, N
collection OXFORD
description A method for controlling the optical properties of a solid-state film over a broad wavelength range is highly desirable and could have significant commercial impact. One such application is smart glazing technology where near-infrared solar radiation is harvested in the winter and reflected it in the summer─an impossibility for materials with fixed thermal and optical properties. Here, we experimentally demonstrate the first spectrally tunable, low-emissivity coating using a chalcogenide-based phase-change material (Ge20Te80), which can modulate the solar heat gain of a window while maintaining neutral-coloration and constant transmission of light at visible wavelengths. We additionally demonstrate the controlled transfer of absorbed near-infrared energy to far-infrared radiation, which can be used to heat a building’s interior and show fast, sub-millisecond switching using transparent electrical heaters integrated on glass substrates. These combined properties result in a smart window that is efficient and aesthetically pleasing─crucial for successful adoption of green technology.
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spelling oxford-uuid:82f2f32d-1d4c-422c-bf19-c37e687b0cef2022-12-19T09:44:46ZReconfigurable low-emissivity optical coating using ultrathin phase change materialsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:82f2f32d-1d4c-422c-bf19-c37e687b0cefEnglishSymplectic ElementsAmerican Chemical Society2021Youngblood, NTalagrand, CPorter, BFGalante, CGKneepkens, STriggs, GSarwat, SGYarmolich, DBonilla, RSHosseini, PTaylor, RABhaskaran, HA method for controlling the optical properties of a solid-state film over a broad wavelength range is highly desirable and could have significant commercial impact. One such application is smart glazing technology where near-infrared solar radiation is harvested in the winter and reflected it in the summer─an impossibility for materials with fixed thermal and optical properties. Here, we experimentally demonstrate the first spectrally tunable, low-emissivity coating using a chalcogenide-based phase-change material (Ge20Te80), which can modulate the solar heat gain of a window while maintaining neutral-coloration and constant transmission of light at visible wavelengths. We additionally demonstrate the controlled transfer of absorbed near-infrared energy to far-infrared radiation, which can be used to heat a building’s interior and show fast, sub-millisecond switching using transparent electrical heaters integrated on glass substrates. These combined properties result in a smart window that is efficient and aesthetically pleasing─crucial for successful adoption of green technology.
spellingShingle Youngblood, N
Talagrand, C
Porter, BF
Galante, CG
Kneepkens, S
Triggs, G
Sarwat, SG
Yarmolich, D
Bonilla, RS
Hosseini, P
Taylor, RA
Bhaskaran, H
Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title_full Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title_fullStr Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title_full_unstemmed Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title_short Reconfigurable low-emissivity optical coating using ultrathin phase change materials
title_sort reconfigurable low emissivity optical coating using ultrathin phase change materials
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