Solid- and solution-state studies of the novel μ-dicyanamide-bridged dinuclear spin-crossover system {[Fe(bztpen)]2[μ-N(CN) 2]}(PF6)3·nH2O

Solid- and solution-state studies of the novel μ-dicyanamide-bridged dinuclear spin-crossover system {[Fe(bztpen)]2[μ-N(CN) 2]}(PF6)3·nH2O

The mononuclear diamagnetic compound {Fe(bztpen)[N(CN)2]} (PF6)CH3OH (1) (bztpen = N-benzyl-N,N′,N′- tris(2-pyridylmethyl)ethylenediamine) has been synthesized and its crystal structure studied. Complex 1 can be considered to be the formal pre-cursor of two new dinuclear, dicyanamide-bridged iron(II...

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Bibliographic Details
Main Authors:	Ortega-Villar, N, Thompson, A, Muñoz, M, Ugalde-Saldívar, V, Goeta, A, Moreno-Esparza, R, Real, J
Format:	Journal article
Language:	English
Published:	2005

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