Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems
Analytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelli...
Main Authors: | , , |
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Format: | Journal article |
Published: |
1993
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Summary: | Analytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelling for both wall-jet and channel flow cell geometries. Exceillent agreement is found. |
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