Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems
Analytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelli...
| Main Authors: | , , |
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| Format: | Journal article |
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1993
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| _version_ | 1797079250614878208 |
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| author | Compton, R Fisher, A Sanders, G |
| author_facet | Compton, R Fisher, A Sanders, G |
| author_sort | Compton, R |
| collection | OXFORD |
| description | Analytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelling for both wall-jet and channel flow cell geometries. Exceillent agreement is found. |
| first_indexed | 2024-03-07T00:43:06Z |
| format | Journal article |
| id | oxford-uuid:83bc0c79-cc11-451d-b696-4fae98ec307f |
| institution | University of Oxford |
| last_indexed | 2024-03-07T00:43:06Z |
| publishDate | 1993 |
| record_format | dspace |
| spelling | oxford-uuid:83bc0c79-cc11-451d-b696-4fae98ec307f2022-03-26T21:46:16ZVoltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systemsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:83bc0c79-cc11-451d-b696-4fae98ec307fSymplectic Elements at Oxford1993Compton, RFisher, ASanders, GAnalytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelling for both wall-jet and channel flow cell geometries. Exceillent agreement is found. |
| spellingShingle | Compton, R Fisher, A Sanders, G Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title | Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title_full | Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title_fullStr | Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title_full_unstemmed | Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title_short | Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems |
| title_sort | voltammetric waveshapes measured in flowing systems mass transport limited tafel analysis of some nonsimple systems |
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