Anion-templated assembly of a [2]catenane.
The first example of a [2]catenane structure to be synthesized using anion templation is described. The nature of the anion template is demonstrated to be crucial to the assembly process, with only chloride anion producing the [2]catenane in acceptable yield. Anion binding studies reveal a dramatic...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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| _version_ | 1797079283303186432 |
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| author | Sambrook, MR Beer, P Wisner, J Paul, R Cowley, A |
| author_facet | Sambrook, MR Beer, P Wisner, J Paul, R Cowley, A |
| author_sort | Sambrook, MR |
| collection | OXFORD |
| description | The first example of a [2]catenane structure to be synthesized using anion templation is described. The nature of the anion template is demonstrated to be crucial to the assembly process, with only chloride anion producing the [2]catenane in acceptable yield. Anion binding studies reveal a dramatic catenation effect on anion selectivity properties as compared to a noncatenated acyclic receptor. |
| first_indexed | 2024-03-07T00:43:36Z |
| format | Journal article |
| id | oxford-uuid:83e10859-753e-494e-af51-8c7eb84bf57f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:43:36Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:83e10859-753e-494e-af51-8c7eb84bf57f2022-03-26T21:47:17ZAnion-templated assembly of a [2]catenane.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:83e10859-753e-494e-af51-8c7eb84bf57fEnglishSymplectic Elements at Oxford2004Sambrook, MRBeer, PWisner, JPaul, RCowley, AThe first example of a [2]catenane structure to be synthesized using anion templation is described. The nature of the anion template is demonstrated to be crucial to the assembly process, with only chloride anion producing the [2]catenane in acceptable yield. Anion binding studies reveal a dramatic catenation effect on anion selectivity properties as compared to a noncatenated acyclic receptor. |
| spellingShingle | Sambrook, MR Beer, P Wisner, J Paul, R Cowley, A Anion-templated assembly of a [2]catenane. |
| title | Anion-templated assembly of a [2]catenane. |
| title_full | Anion-templated assembly of a [2]catenane. |
| title_fullStr | Anion-templated assembly of a [2]catenane. |
| title_full_unstemmed | Anion-templated assembly of a [2]catenane. |
| title_short | Anion-templated assembly of a [2]catenane. |
| title_sort | anion templated assembly of a 2 catenane |
| work_keys_str_mv | AT sambrookmr aniontemplatedassemblyofa2catenane AT beerp aniontemplatedassemblyofa2catenane AT wisnerj aniontemplatedassemblyofa2catenane AT paulr aniontemplatedassemblyofa2catenane AT cowleya aniontemplatedassemblyofa2catenane |