Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.

Molecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing...

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Main Authors: Saywell, A, Sprafke, J, Esdaile, L, Britton, A, Rienzo, A, Anderson, H, O'Shea, J, Beton, P
Format: Journal article
Language:English
Published: 2010
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author Saywell, A
Sprafke, J
Esdaile, L
Britton, A
Rienzo, A
Anderson, H
O'Shea, J
Beton, P
author_facet Saywell, A
Sprafke, J
Esdaile, L
Britton, A
Rienzo, A
Anderson, H
O'Shea, J
Beton, P
author_sort Saywell, A
collection OXFORD
description Molecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing of polymer strands (see scheme), a longer correlation length as compared with solvated oligomers is observed. Copyright © 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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spelling oxford-uuid:84bb4f7a-b4fa-4f49-a096-2db85bb041f02022-03-26T21:53:03ZConformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:84bb4f7a-b4fa-4f49-a096-2db85bb041f0EnglishSymplectic Elements at Oxford2010Saywell, ASprafke, JEsdaile, LBritton, ARienzo, AAnderson, HO'Shea, JBeton, PMolecular worms: Porphyrin polymers and oligomers are deposited on a Au(111) surface using electrospray deposition and are shown to adopt an arrangement where chains from neighboring molecules are interdigitated. Although the flexible nature of the polymers gives rise to sharp kinks and the crossing of polymer strands (see scheme), a longer correlation length as compared with solvated oligomers is observed. Copyright © 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
spellingShingle Saywell, A
Sprafke, J
Esdaile, L
Britton, A
Rienzo, A
Anderson, H
O'Shea, J
Beton, P
Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title_full Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title_fullStr Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title_full_unstemmed Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title_short Conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface.
title_sort conformation and packing of porphyrin polymer chains deposited using electrospray on a gold surface
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