High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions.

High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions.

A new class of transition metal cluster is described, [Rh(6)(PR(3))(6)H(12)][BAr(F)(4)](2) (R = (i)Pr (1a), Cy (2a); BAr(F)(4) = [B{C(6)H(3)(CF(3))(2)}(4)](-)). These clusters are unique in that they have structures exactly like those of early transition metal clusters with edge-bridging pi-donor li...

Descrizione completa

Dettagli Bibliografici
Autori principali:	Brayshaw, S, Ingleson, M, Green, J, McIndoe, J, Raithby, P, Kociok-Köhn, G, Weller, A
Natura:	Journal article
Lingua:	English
Pubblicazione:	2006

Documenti analoghi

Sequential reduction of high hydride count octahedral rhodium clusters [Rh6(PR3)6H12][BArF4]2: redox-switchable hydrogen storage.
di: Brayshaw, S, et al.
Pubblicazione: (2007)

High hydride count rhodium octahedra: Towards electrochemically switchable hydrogen storage devices
di: Weller, A, et al.
Pubblicazione: (2006)

Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2.
di: Douglas, T, et al.
Pubblicazione: (2008)

Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2.
di: Brayshaw, S, et al.
Pubblicazione: (2005)

[(iPr3P)6Rh6H12]2+: a high-hydride content octahedron that bridges the gap between late and early transition metal clusters.
di: Ingleson, M, et al.
Pubblicazione: (2004)

A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond.
di: Brayshaw, S, et al.
Pubblicazione: (2006)

Dihydrogen complexes of rhodium: [RhH2(H2)x (PR3)2]+ (R = Cy, iPr; x = 1, 2).
di: Ingleson, M, et al.
Pubblicazione: (2005)

Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.
di: Molinos, E, et al.
Pubblicazione: (2007)

[Rh(7)(PiPr(3))(6)H(18)][BAr(F) (4)](2): a molecular Rh(111) surface decorated with 18 hydrogen atoms.
di: Brayshaw, S, et al.
Pubblicazione: (2007)

Rhodium(III) complexes that contain Rh...C-C and Rh...C-H agostic bonds
di: Brayshaw, S, et al.
Pubblicazione: (2006)

Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η 6-fluorobenzene complexes probed using collision-induced dissociation
di: Pike, S, et al.
Pubblicazione: (2015)

A DFT based investigation into the electronic structure and properties of hydride rich rhodium clusters.
di: Brayshaw, S, et al.
Pubblicazione: (2007)

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).
di: Hiney, R, et al.
Pubblicazione: (2010)

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).
di: Douglas, T, et al.
Pubblicazione: (2008)

Storing and releasing hydrogen with a redox switch.
di: Brayshaw, S, et al.
Pubblicazione: (2006)

[1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11))
di: Molinos, E, et al.
Pubblicazione: (2006)

Structural isomers and reactivity for Rh6 and Rh6+.
di: Harding, D, et al.
Pubblicazione: (2006)

Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H-2 binding materials on a surface
di: Hiney, R, et al.
Pubblicazione: (2009)

Cationic iridium phosphines partnered with [closo-CB11H6Br6](_): (PPh3)(2)Ir(H)(2)(closo-CB11H6Br6) and [(PPh3)(2)Ir(eta(2)-C2H4)(3)][closo-CB11H6Br6]. Relevance to counterion effects in olefin hydrogenation
di: Rifat, A, et al.
Pubblicazione: (2004)

B-C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments
di: Ingleson, M, et al.
Pubblicazione: (2005)

Exploring the mechanism of the hydroboration of alkenes by amine-boranes catalysed by [Rh(xantphos)](+)
di: Johnson, H, et al.
Pubblicazione: (2014)

Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+
di: Johnson, H, et al.
Pubblicazione: (2014)

Rhodium phosphine olefin complexes of the weakly coordinating anions [BAr4F](-) and [1-closo-CB11H6Br6](-). Kinetic versus thermodynamic factors in anion coordination and complex reactivity
di: Douglas, T, et al.
Pubblicazione: (2007)

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex.
di: Moxham, G, et al.
Pubblicazione: (2007)

C-C sigma complexes of rhodium.
di: Brayshaw, S, et al.
Pubblicazione: (2007)

Charge localization by static and dynamic distortions of the MnO6 octahedra in perovskite manganites.
di: Radaelli, P, et al.
Pubblicazione: (1996)

Dehydrocoupling of phosphine-boranes using the [RhCp∗Me(PMe3)(CH2Cl2)][BArF 4] precatalyst: Stoichiometric and catalytic studies
di: Hooper, T, et al.
Pubblicazione: (2015)

Sequential dehydrogenative borylation/hydrogenation route to polyethyl-substituted, weakly coordinating carborane anions
di: Molinos, E, et al.
Pubblicazione: (2007)

Reversible binding of dihydrogen in multimetallic complexes
di: Weller, A, et al.
Pubblicazione: (2007)

Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
di: Hyde, S, et al.
Pubblicazione: (2018)

Investigation of the synthesis of {Mo(eta(5)-C5H5)(CO)(3)}(+) fragments partnered with the monoanionic carboranes [closo-CB11H11Br](-), [closo-CB11H6Br6](-) and [closo-HCB11Me11](-) by silver salt metathesis and hydride abstraction
di: Patmore, N, et al.
Pubblicazione: (2003)

Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3-, [Rh@Sn12]3-, [Rh2@Sn17]6- and the first triply-fused stannide, [Rh3@Sn24]5
di: Liu, C, et al.
Pubblicazione: (2019)

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]
di: Rifat, A, et al.
Pubblicazione: (2003)

Nitric oxide decomposition on small rhodium clusters, Rh(n)+/-
di: Anderson, M, et al.
Pubblicazione: (2006)

Nitric oxide decomposition on small rhodium clusters, Rh(n)+/-.
di: Anderson, M, et al.
Pubblicazione: (2006)

BARF: Bundle-Adjusting Neural Radiance Fields
di: Lin, Chen-Hsuan, et al.
Pubblicazione: (2022)

Coupling an electrospray ionization mass spectrometer with a glovebox: A straightforward, powerful, and convenient combination for analysis of air-sensitive organometallics
di: Lubben, A, et al.
Pubblicazione: (2008)

[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
di: Chaplin, AB, et al.
Pubblicazione: (2011)

Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids
di: Jin, L, et al.
Pubblicazione: (2019)

The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
di: Moxham, G, et al.
Pubblicazione: (2006)