High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions.

High hydride count rhodium octahedra, [Rh6(PR3)6H12][BArF4]2: synthesis, structures, and reversible hydrogen uptake under mild conditions.

A new class of transition metal cluster is described, [Rh(6)(PR(3))(6)H(12)][BAr(F)(4)](2) (R = (i)Pr (1a), Cy (2a); BAr(F)(4) = [B{C(6)H(3)(CF(3))(2)}(4)](-)). These clusters are unique in that they have structures exactly like those of early transition metal clusters with edge-bridging pi-donor li...

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Những tác giả chính:	Brayshaw, S, Ingleson, M, Green, J, McIndoe, J, Raithby, P, Kociok-Köhn, G, Weller, A
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2006

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