COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM
Relaxation of the N″ = 15 Λ doublets of CH(X 2Π) produced in the two-photon dissociation of ketene at 279.3 nm has been observed in the presence of Ar. An initially equilibrated nascent Λ doublet population is seen to be removed in such a way that the component of A″ symmetry (π orbital perpendicula...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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1994
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| _version_ | 1826282732638961664 |
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| author | Ball, S Hancock, G Heal, M |
| author_facet | Ball, S Hancock, G Heal, M |
| author_sort | Ball, S |
| collection | OXFORD |
| description | Relaxation of the N″ = 15 Λ doublets of CH(X 2Π) produced in the two-photon dissociation of ketene at 279.3 nm has been observed in the presence of Ar. An initially equilibrated nascent Λ doublet population is seen to be removed in such a way that the component of A″ symmetry (π orbital perpendicular to the plane of rotation) dominates. The application of recent theory describing collisions of 2Π diatomics with closed shell atoms is briefly discussed. |
| first_indexed | 2024-03-07T00:48:17Z |
| format | Journal article |
| id | oxford-uuid:85725d89-398d-4081-b66f-de0cf416fa6c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:48:17Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:85725d89-398d-4081-b66f-de0cf416fa6c2022-03-26T21:57:40ZCOLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NMJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:85725d89-398d-4081-b66f-de0cf416fa6cEnglishSymplectic Elements at Oxford1994Ball, SHancock, GHeal, MRelaxation of the N″ = 15 Λ doublets of CH(X 2Π) produced in the two-photon dissociation of ketene at 279.3 nm has been observed in the presence of Ar. An initially equilibrated nascent Λ doublet population is seen to be removed in such a way that the component of A″ symmetry (π orbital perpendicular to the plane of rotation) dominates. The application of recent theory describing collisions of 2Π diatomics with closed shell atoms is briefly discussed. |
| spellingShingle | Ball, S Hancock, G Heal, M COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title | COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title_full | COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title_fullStr | COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title_full_unstemmed | COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title_short | COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM |
| title_sort | collisional behavior with ar of the lambda doublets of ch x 2 pi n 15 produced in the 2 photon dissociation of ch2co at 279 3 nm |
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