COLLISIONAL BEHAVIOR WITH AR OF THE LAMBDA-DOUBLETS OF CH(X(2)PI) N''=15 PRODUCED IN THE 2-PHOTON DISSOCIATION OF CH2CO AT 279.3 NM

Relaxation of the N″ = 15 Λ doublets of CH(X 2Π) produced in the two-photon dissociation of ketene at 279.3 nm has been observed in the presence of Ar. An initially equilibrated nascent Λ doublet population is seen to be removed in such a way that the component of A″ symmetry (π orbital perpendicula...

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Bibliographic Details
Main Authors: Ball, S, Hancock, G, Heal, M
Format: Journal article
Language:English
Published: 1994