Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation

Pyrene-appended ytterbium complexes have been prepared using Ugi reactions to vary the chromophore-lanthanide separation. Formation of the ytterbium(iii) excited state is sensitised via both the singlet and triplet excited states of the chromophore. Energy transfer from the latter is relatively slow...

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Main Authors: Watkis, A, Hueting, R, Sørensen, T, Tropiano, M, Faulkner, S
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2015
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author Watkis, A
Hueting, R
Sørensen, T
Tropiano, M
Faulkner, S
author_facet Watkis, A
Hueting, R
Sørensen, T
Tropiano, M
Faulkner, S
author_sort Watkis, A
collection OXFORD
description Pyrene-appended ytterbium complexes have been prepared using Ugi reactions to vary the chromophore-lanthanide separation. Formation of the ytterbium(iii) excited state is sensitised via both the singlet and triplet excited states of the chromophore. Energy transfer from the latter is relatively slow, and gives rise to oxygen-dependent luminescence.
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spelling oxford-uuid:8593ad3c-4aee-41a9-94e0-4b56cffa73772022-03-26T21:58:26ZControlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8593ad3c-4aee-41a9-94e0-4b56cffa7377EnglishSymplectic Elements at OxfordRoyal Society of Chemistry2015Watkis, AHueting, RSørensen, TTropiano, MFaulkner, SPyrene-appended ytterbium complexes have been prepared using Ugi reactions to vary the chromophore-lanthanide separation. Formation of the ytterbium(iii) excited state is sensitised via both the singlet and triplet excited states of the chromophore. Energy transfer from the latter is relatively slow, and gives rise to oxygen-dependent luminescence.
spellingShingle Watkis, A
Hueting, R
Sørensen, T
Tropiano, M
Faulkner, S
Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title_full Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title_fullStr Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title_full_unstemmed Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title_short Controlling energy transfer in ytterbium complexes: oxygen dependent lanthanide luminescence and singlet oxygen formation
title_sort controlling energy transfer in ytterbium complexes oxygen dependent lanthanide luminescence and singlet oxygen formation
work_keys_str_mv AT watkisa controllingenergytransferinytterbiumcomplexesoxygendependentlanthanideluminescenceandsingletoxygenformation
AT huetingr controllingenergytransferinytterbiumcomplexesoxygendependentlanthanideluminescenceandsingletoxygenformation
AT sørensent controllingenergytransferinytterbiumcomplexesoxygendependentlanthanideluminescenceandsingletoxygenformation
AT tropianom controllingenergytransferinytterbiumcomplexesoxygendependentlanthanideluminescenceandsingletoxygenformation
AT faulkners controllingenergytransferinytterbiumcomplexesoxygendependentlanthanideluminescenceandsingletoxygenformation