Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals
PbS nanocrystals are synthesized using colloidal techniques and have their surfaces capped with oleic acid. The absorption band edge of the PbS nanocrystals is tuned between 900 and 580 nm. The PbS nanocrystals exhibit tuneable photoluminescence with large non-resonant Stokes shifts of up to 500 meV...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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| _version_ | 1826283130452967424 |
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| author | Warner, J Thomsen, E Watt, A Heckenberg, N Rubinsztein-Dunlop, H |
| author_facet | Warner, J Thomsen, E Watt, A Heckenberg, N Rubinsztein-Dunlop, H |
| author_sort | Warner, J |
| collection | OXFORD |
| description | PbS nanocrystals are synthesized using colloidal techniques and have their surfaces capped with oleic acid. The absorption band edge of the PbS nanocrystals is tuned between 900 and 580 nm. The PbS nanocrystals exhibit tuneable photoluminescence with large non-resonant Stokes shifts of up to 500 meV. The magnitude of the Stokes shift is found to be dependent upon the size of PbS nanocrystals. Time-resolved photoluminescence spectroscopy of the PbS nanocrystals reveals that the photoluminescence has an extraordinarily long lifetime of 1 μs. This long fluorescence lifetime is attributed to the effect of dielectric screening similar to that observed in other IV-VI semiconductor nanocrystals. |
| first_indexed | 2024-03-07T00:54:18Z |
| format | Journal article |
| id | oxford-uuid:877ee8fd-d774-4c00-a125-1831b22e3ad2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T00:54:18Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:877ee8fd-d774-4c00-a125-1831b22e3ad22022-03-26T22:11:02ZTime-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:877ee8fd-d774-4c00-a125-1831b22e3ad2EnglishSymplectic Elements at Oxford2005Warner, JThomsen, EWatt, AHeckenberg, NRubinsztein-Dunlop, HPbS nanocrystals are synthesized using colloidal techniques and have their surfaces capped with oleic acid. The absorption band edge of the PbS nanocrystals is tuned between 900 and 580 nm. The PbS nanocrystals exhibit tuneable photoluminescence with large non-resonant Stokes shifts of up to 500 meV. The magnitude of the Stokes shift is found to be dependent upon the size of PbS nanocrystals. Time-resolved photoluminescence spectroscopy of the PbS nanocrystals reveals that the photoluminescence has an extraordinarily long lifetime of 1 μs. This long fluorescence lifetime is attributed to the effect of dielectric screening similar to that observed in other IV-VI semiconductor nanocrystals. |
| spellingShingle | Warner, J Thomsen, E Watt, A Heckenberg, N Rubinsztein-Dunlop, H Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title | Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title_full | Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title_fullStr | Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title_full_unstemmed | Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title_short | Time-resolved photoluminescence spectroscopy of ligand-capped PbS nanocrystals |
| title_sort | time resolved photoluminescence spectroscopy of ligand capped pbs nanocrystals |
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