Convenient solution route to alkylated pentalene ligands: New metal monoalkylpentalenyl complexes

Convenient solution route to alkylated pentalene ligands: New metal monoalkylpentalenyl complexes

Carbene-induced rearrangement of 8,8-dibromobicyclo[5.1.0]octa-2,4-dienes and subsequent in situ deprotonation of the dihydropentalenes formed represents a straightforward and versatile solution route to pentalene ligands for use in organometallic chemistry. We report here the synthesis of 6-alkyl-s...

Full description

Bibliographic Details
Main Authors:	Jones, S, Roussel, P, Hascall, T, O'Hare, D
Format:	Journal article
Language:	English
Published:	2006

Similar Items

Pentalene complexes of chromium, manganese and rhenium.
by: Jones, S, et al.
Published: (2002)

A novel coordination mode for pentalene in trinuclear chromium complexes.
by: Jones, S, et al.
Published: (2003)

Pentalene complexes of group 7 metal carbonyls: an organometallic mixed-valence system with very large metal-metal electronic coupling.
by: Jones, S, et al.
Published: (2002)

Bonding in pentalene complexes and their recent applications
by: Cloke, F, et al.
Published: (2016)

The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry.
by: Ashley, A, et al.
Published: (2007)

[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
by: Jones, S, et al.
Published: (2003)

Complexes of iron(II) with silylated pentalene ligands; building blocks for homo- and heterobimetallics
by: Kilpatrick, AFR, et al.
Published: (2016)

New Pathways to Precursors of Pentalene
by: Shaochun You, et al.
Published: (1996-01-01)

Single-molecule magnet properties of a monometallic dysprosium pentalene complex
by: Kilpatrick, AFR, et al.
Published: (2018)

Synthesis and Reactions of Dibenzo[a,e]pentalenes
by: Masaichi Saito
Published: (2010-04-01)

Silicon-bridged bis(cyclohexadienyl) iron complexes: the first structurally characterised [1(4)]ferrocenophane
by: Hascall, T, et al.
Published: (2001)

Ligand-centered oxidation in a diiron s-indacene complex
by: Roussel, P, et al.
Published: (2000)

Bonding in complexes of bis(pentalene)dititanium, Ti2(C8H6)2
by: Kilpatrick, A, et al.
Published: (2015)

Electronic structures of mixed-sandwich complexes of cyclopentadienyl and Hydrotris(pyrazolyl)borate ligands with 3d transition metals.
by: Brunker, T, et al.
Published: (2003)

Convenient route to education
by: The, Sun
Published: (2015)

Synthesis and characterization of a bimetallic boratabenzene cobalt complex
by: Hascall, T, et al.
Published: (2004)

Reactivity of a dititanium bis(pentalene) complex toward heteroallenes and main-group element–element bonds
by: Kilpatrick, A, et al.
Published: (2016)

Synthesis, structures, and redox properties of mixed-sandwich complexes of cyclopentadienyl and hydrotris(pyrazolyl)borate ligands with first-row transition metals
by: Brunker, T, et al.
Published: (2002)

Density Functional Study of Metal-to-Ligand Charge Transfer and Hole-Hopping in Ruthenium(II) Complexes with Alkyl-Substituted Bipyridine Ligands
by: Salmahaminati, et al.
Published: (2020-12-01)

Heteroleptic Calcium Complexes Supported by a Phenoxy-Imine NON Ligand: Polymerization of Cyclic Esters by a Ligand-Assisted, Activated-Monomer Mechanism
by: Jones, RL, et al.
Published: (2024)

Scandium chloride, alkyl and phenyl complexes of diamido-donor ligands
by: Ward, B, et al.
Published: (2002)

Cerium(III) and cerium(IV) bis(eta(8)-pentalene) sandwich complexes: Synthetic, structural, spectroscopic, and theoretical studies
by: Balazs, G, et al.
Published: (2007)

Variable coordination modes of hydrotris(3-isopropyl-4-bromopyrazolyl)borate (Tp') in Fe(II), Mn(II), Cr(II), and Cr(III) Complexes: formation of MTp'Cl (M = Fe and Mn), structural isomerism in CrTp'(2), and the observation of Tp' (-) as an uncoordinated anion.
by: Brunker, T, et al.
Published: (2001)

The Effect of Benzannulation on the Structures, Reactivity and Molecular Dynamics of Indenes, Pentalenes, Azulenes and Related Molecules
by: Michael J. McGlinchey
Published: (2022-06-01)

An alkylation route to carbo- and heteroaromatic amino acids
by: Raymond C. F. Jones, et al.
Published: (2006-10-01)

Bis(pentalene)dititanium chemistry: C–H, C–X and H–H bond activation
by: Tsoureas, N, et al.
Published: (2018)

Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
by: Bruno de la Torre, et al.
Published: (2020-09-01)

Metal-ligand cooperative iridium complex catalyzed C-alkylation of oxindole and 1,3-dimethylbarbituric acid using alcohols
by: Ao Song, et al.
Published: (2023-08-01)

Ligand-enabled Ni-catalysed enantioconvergent intermolecular Alkyl-Alkyl cross-coupling between distinct Alkyl halides
by: Wen-Tao Zhao, et al.
Published: (2023-05-01)

Pendant ancillary ligand switches off auto-oxidation of group 13 metal alkyl compounds bearing non-bulky alkyl groups.
by: Issam Kobrsi
Published: (2014-01-01)

A Dichromium(II) BiS(eta(8)-pentalene) double-sandwich complex with a spin equilibrium: Synthetic, structural, magnetic, and theoretical studies
by: Balazs, G, et al.
Published: (2008)

Triple-decker transition metal complexes bridged by a single carbocyclic ring
by: Beck, V, et al.
Published: (2004)

Rational design and convenient synthesis of a novel family of ruthenium complexes with O,N-bidentate ligands
by: Drozdzak Renate, et al.
Published: (2005-09-01)

Synthetic Routes to Crystalline Complex Metal Alkyl Carbonates and Hydroxycarbonates via Sol–Gel Chemistry—Perspectives for Advanced Materials in Catalysis
by: Schirin Hanf, et al.
Published: (2022-05-01)

Halide abstraction as a route to cationic transition-metal complexes containing two-coordinate gallium and indium ligand systems
by: Bunn, N, et al.
Published: (2005)

Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
by: Aguirre-Etcheverry, P, et al.
Published: (2010)

Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
by: Aguirre-Etcheverry, P, et al.
Published: (2010)

A Convenient, Rapid, Conventional Heating Route to MIDA Boronates
by: Andrew McGown, et al.
Published: (2022-08-01)

A Convenient Synthesis Route of Hydroxyapatite from Egg Shells
by: Muhammad Aftab Akram, et al.
Published: (2011-12-01)

Reaction of polyamines with diethyloxalate: a convenient route for the synthesis of tetraazacycloalkanes
by: Franck Denat, et al.
Published: (2006-05-01)